2002
DOI: 10.1116/1.1450589
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Recent advances in resists for 157 nm microlithography

Abstract: The synthesis and characterization of several new fluoropolymers designed for use in the formulation of photoresists for exposure at 157 nm will be described. The design of these platforms has in some cases been inspired by ab initio quantum mechanical calculations of excited state transition energies and by interpretation of gas phase VUV spectrophotometric data. We have explored anionic polymerizations, free radical polymerizations, metal-catalyzed addition polymerizations and metal-catalyzed copolymerizatio… Show more

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Cited by 14 publications
(9 citation statements)
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“…Since it is not easy to prepare homopolymers of α‐trifluoromethacrylic monomers using free‐radical initiators, two different approaches have been attempted. Anionic polymerization was used to prepare α‐trifluoromethyl acrylate polymers 70. An alternative method involved radical copolymerization with other monomers.…”
Section: Fluorinated Polymer Resists For 157 Nm Lithographymentioning
confidence: 99%
See 1 more Smart Citation
“…Since it is not easy to prepare homopolymers of α‐trifluoromethacrylic monomers using free‐radical initiators, two different approaches have been attempted. Anionic polymerization was used to prepare α‐trifluoromethyl acrylate polymers 70. An alternative method involved radical copolymerization with other monomers.…”
Section: Fluorinated Polymer Resists For 157 Nm Lithographymentioning
confidence: 99%
“…Copolymers of norbornenes with tetrafluoroethlyene have also been prepared. To incorporate polar functional groups for proper adhesion and solubility, copolymers of polar norbornenes70 and/or terpolymer systems with α‐monofluoroacrylates78,79,80 have been attempted. Our approach was made using trifluoroacrylate and/or 2,2,3,4,4‐pentafluorobut‐3‐enoic acid ester instead of tetrafluoroethylene.…”
Section: Fluorinated Polymer Resists For 157 Nm Lithographymentioning
confidence: 99%
“…[16][17][18] The most prominent application of lithography is that of UV-mask lithography, which is widely used in the semiconductor industry. [20][21][22][23][24][25][26] A publication by Grunze et al is of particular note because it introduces the possibility for chemical lithography using an electron beam. Therefore, industry and academia invest intensive effort in developing UV and deep-UV lithographic techniques, which can provide structural resolution down to 80 nm.…”
Section: Introductionmentioning
confidence: 99%
“…In particular, in the in situ method inorganic precursors of NPs can be introduced in monomers before the polymerization, or after the polymerization. NP formation can occur either by chemically reduction [ 93 ], thermal decomposition [ 94 ] or induced by light (UV) irradiation [ 95 ]. In the sol-gel method, solid precursors and low temperature processes are used for covalent bond formation in solutions [ 7 ].…”
Section: Nanocomposite Materialsmentioning
confidence: 99%