Recent Advances in Research on Carbon Nanotube–Polymer Composites

Byrne, Michele T.; Gun’ko, Yurii K.

doi:10.1002/adma.200901545

Cited by 816 publications

(525 citation statements)

References 216 publications

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“…Furthermore, the incorporation of micro-scale fillers, nanoparticles, nanotubes and nanofibers as filler materials is now at the forefront of materials research to produce safe, high-performance composite structures (3). Carbon nanotubes (CNTs) have been demonstrated to exhibit great potential as nanofillers for polymer-based nanocomposites owing to their unique structure and excellent mechanical chemical, electronic and thermal properties (4).…”

Section: Introductionmentioning

confidence: 99%

Investigation into the toughening mechanism of epoxy reinforced with multi-wall carbon nanotubes

Zhang

Zhai

et al. 2015

E-Polymers

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This study reports the reinforcement and fracture toughening mechanism of pristine multi-walled carbon nanotubes (MWCNTs) on epoxy matrix. The tensile strength and fracture energy (G IC ) of the epoxy polymer increased simultaneously upon the addition of a small amount of MWCNTs. The fracture surfaces of single-edgenotch three-point bending test specimens were analysed by scanning electron microscopy, and the double-notch four-point bending technique was used to investigate the fracture process by transmission electron microscopy, respectively. MWCNT pull-out and subsequent plastic void growth were found; meanwhile, fracture of MWCNTs was observed along the crack propagation path. The theoretical model of shearing band initiated by the stress concentrations around the MWCNTs is the dominant toughening mechanism. While the crack bridging of MWCNTs and the plastic void growth of epoxy also have a toughening effect.

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Section: Introductionmentioning

confidence: 99%

Investigation into the toughening mechanism of epoxy reinforced with multi-wall carbon nanotubes

Zhang

Zhai

et al. 2015

E-Polymers

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“…19,20 Non-covalent functionalization with conjugated polymers is particularly attractive, because chemical groups are attached without disrupting the bonding network of the CNT, whereas covalent functionalization introduces atomic defects and internal stress, which can deteriorate the mechanical properties. 21 Unique electrical and optical properties have been demonstrated for CNTs interacting with conjugated polymers. 22,23 It is desirable to optimize the non-covalent intermolecular interactions in view of achieving a strong interfacial binding in the composite.…”

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confidence: 99%

Non-covalent functionalization of single wall carbon nanotubes and graphene by a conjugated polymer

Jiwuer

Abdurahman

Gülseren

et al. 2014

Applied Physics Letters

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We report first-principles calculations on the binding of poly[(9,9-bis-(6-bromohexylfluorene-2,7-diyl)-co-(benzene-1,4-diyl)] to a (8,0) single wall carbon nanotube (SWCNT) and to graphene. Considering different relative orientations of the subsystems, we find for the generalized gradient approximation a non-binding state, whereas the local density approximation predicts reasonable binding energies. The results coincide after inclusion of van der Waals corrections, which demonstrates a weak interaction between the polymer and SWCNT/graphene, mostly of van der Waals type. Accordingly, the density of states shows essentially no hybridization. The physisorption mechanism explains recent experimental observations and suggests that the conjugated polymer can be used for non-covalent functionalization. © 2014 AIP Publishing LLC

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“…We assume that the well-dispersed CNT improved not only the electrical conduction path, but also the mechanical properties of the polymer electrolyte, known as one of the typical effect of CNT-based additives. 14 …”

Section: Resultsmentioning

confidence: 99%

Study of Degradation Processes of Carbon Negative Electrodes for All-solid Lithium Polymer Batteries

et al. 2014

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Degradation processes of carbon negative electrodes for all-solid lithium polymer batteries were investigated using X-ray diffraction (XRD), electrochemical impedance spectroscopy (EIS) and Scanning Electron Microscope (SEM). The cycling performances of the electrodes are significantly affected by the mixing speed of the electrode slurry. The cross-sectional SEM images of the electrodes containing vapor-grown carbon fiber (VGCF) show that more voids remained in the electrodes, if the slurry was mixed at high speed. The voids in the composite electrode expand and increase during the cycling test of the cell resulting in the capacity fading. On the other hand, the electrodes containing carbon nanotubes (CNT) show an opposite trend, because the high mixing speed improves the dispersibility of the CNT resulting in the formation of the less voids in the electrode. The electrode containing both VGCF and CNT prepared at high mixing speed shows the best cycleability among all the electrodes. In spite of some voids initially form in the electrode, the CNT seems to have prevented further increase and expansion of the voids.

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Recent Advances in Research on Carbon Nanotube–Polymer Composites

Cited by 816 publications

References 216 publications

Investigation into the toughening mechanism of epoxy reinforced with multi-wall carbon nanotubes

Investigation into the toughening mechanism of epoxy reinforced with multi-wall carbon nanotubes

Non-covalent functionalization of single wall carbon nanotubes and graphene by a conjugated polymer

Study of Degradation Processes of Carbon Negative Electrodes for All-solid Lithium Polymer Batteries

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