Abstract:Photocatalytic organic conversion is considered an efficient, environmentally friendly, and energy-saving strategy for organic synthesis. In recent decades, the molecular cage has emerged as a creative functional material with broad...
“…3 All these elements are combined in slider-on-deck machinery 4 with either on/off or up/down regulation of catalysis. 5 Since nanoscale metallocages are well established in sensing, 6 catalysis, 7 and highly selective binding, 8 interconnecting dynamic molecular machines and functional nanocages may offer new venues for functional applications.…”
The full interconversion of a multicomponent slider-on-deck and a palladium(ii) capsule is used to establish the up/down regulation of a copper(i)-catalyzed aza Hopf cyclization that is reported by characteristic fluorescence changes.
“…3 All these elements are combined in slider-on-deck machinery 4 with either on/off or up/down regulation of catalysis. 5 Since nanoscale metallocages are well established in sensing, 6 catalysis, 7 and highly selective binding, 8 interconnecting dynamic molecular machines and functional nanocages may offer new venues for functional applications.…”
The full interconversion of a multicomponent slider-on-deck and a palladium(ii) capsule is used to establish the up/down regulation of a copper(i)-catalyzed aza Hopf cyclization that is reported by characteristic fluorescence changes.
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