Recent Advances in Plasticizers

doi:10.5772/2228

2012

DOI: 10.5772/2228

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Recent Advances in Plasticizers

Abstract: He teaches Polymer Science and Engineering courses. He served as an Assistant Manager in Samsung Cheil Industries, South Korea, and worked on the development of heat resistant polymers, organic glass, and block copolymers as impact modifiers and compatibilizers for engineering polymers. He served as a post-doctoral fellow at

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Cited by 20 publications

References 207 publications

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Evaluation of a Ru‐bipod Complex as a Redox Transducer for Membrane‐Based Voltammetry of Anions**

Kalaei,

Ide,

Haga

et al. 2023

ChemElectroChem

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Molecular redox compounds show promise for the development of solid contact ion selective electrodes (SC‐ISEs) for anion determinations. In this work, a hydrophobic bis‐tridentate Ru‐bipod complex was studied as a molecular redox transducer in voltammetric SC‐ISEs. Thin film voltammetric behavior was achieved in films comprised of the Ru‐bipod complex, polyvinylchloride (PVC) and a plasticiser, nitrophenyloctylether (NPOE). Importantly, the choice of plasticiser had a significant effect on the SC‐ISE response of the Ru‐bipod complex; i. e., voltammetric responses of the Ru‐bipod complex in NPOE films were sharper and more intense than in bis(2‐ethylhexyl) sebacate (DOS) films. Moreover, addition of tetradodecylammonium tetrakis(4‐chlorophenyl)borate (ETH 500) to the membrane had an unfavorable impact on detection of anions due to oxidation of this salt in the film. Although the thin film electrode showed close‐to‐Nernstian behavior in anion responses, the detection responses in the presence of very hydrophilic anions such as sulfate ion were shifted to higher potentials (>1 V) with a subsequent loss of sensitivity. Overall, the Ru‐bipod complex operates as a simple transducer in SC‐ISEs with benefits in anion detection.

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Evaluation of a Ru‐bipod Complex as a Redox Transducer for Membrane‐Based Voltammetry of Anions**

Kalaei,

Ide,

Haga

et al. 2023

ChemElectroChem

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Poly(ε‐caprolactone)‐based additives: Plasticization efficacy and migration resistance

Jamarani

Halloran

Panchal

et al. 2021

Vinyl Additive Technology

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A family of poly(caprolactone) (PCL)-based oligomeric additives was evaluated as plasticizers for poly(vinyl chloride) (PVC). We found that the entire family of additives, which consist of a PCL core, diester linker, and alkyl chain cap, were effective plasticizers that improve migration resistance. The elongation at break and tensile strength of the blends made with the PCL-based additives were comparable to blends prepared with diisononyl phthalate (DINP), a plasticizer typically used industrially, and diheptyl succinate (DHPS), an alternative biodegradable plasticizer. Increasing concentration was found to decrease glass transition temperature (T g ) and increase elongation at break, confirming their role as functional plasticizers. We found that all of the PCL-based plasticizers exhibited significantly reduced leaching into hexanes compared to DINP and DHPS. The PCL-based plasticizers with shorter carbon chain lengths reduced leaching more than those with longer carbon chain lengths.

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Water monitoring with an automated smart sensor supported with solar power for real-time and long range detection of ferrous iron

Ozer,

Agir,

Borch

2024

Analyst

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Recent Advances in Plasticizers

Cited by 20 publications

References 207 publications

Evaluation of a Ru‐bipod Complex as a Redox Transducer for Membrane‐Based Voltammetry of Anions**

Evaluation of a Ru‐bipod Complex as a Redox Transducer for Membrane‐Based Voltammetry of Anions**

Poly(ε‐caprolactone)‐based additives: Plasticization efficacy and migration resistance

Water monitoring with an automated smart sensor supported with solar power for real-time and long range detection of ferrous iron

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