Recent Advances in Ligand-Controlled Regio- or Stereodivergent Transition-Metal-Catalyzed Hydroelementation (H[E]) (E = H, B, Si, Ge) of C–C Unsaturated Systems
Sehoon Park
Abstract:Reductive functionalization of C-C unsaturated systems including alkenes and alkynes with a range of hydroelements (H[E]) is one of the most fundamental, but highly practical methods in the synthesis of functionalized hydrocarbons. Since the resultant hydrocarbon products have strong applicability as a synthetic intermediate, numerous homogeneous orano(metallic) catalysts have been intensively practiced up to date for the reductive functionalization reactions. In particular, well-defined transition metal-based… Show more
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