2023
DOI: 10.1039/d3mh00135k
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Recent advances in in situ and operando characterization techniques for Li7La3Zr2O12-based solid-state lithium batteries

Abstract: Li7La3Zr2O12 (LLZO)-based solid-state lithium batteries (SSLBs) have emerged as one of the most promising energy storage systems due to the potential properties of solid-state electrolytes (SSEs), such as ionic conductivity,...

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Cited by 15 publications
(8 citation statements)
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References 255 publications
(402 reference statements)
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“…The authors acknowledge pioneering research in this field in the very early years. We also acknowledge the previous comprehensive reviews on the development of SSBs , and reviews specifically on the SEs or electrodes. Although some other previous reviews have a similar focus (on the challenges of the interface issue) to this work, , new materials, strategies, and interface designs have been emerging in very recent years. This review provides essential updates on the important advances in the topic.…”
Section: Introductionmentioning
confidence: 93%
“…The authors acknowledge pioneering research in this field in the very early years. We also acknowledge the previous comprehensive reviews on the development of SSBs , and reviews specifically on the SEs or electrodes. Although some other previous reviews have a similar focus (on the challenges of the interface issue) to this work, , new materials, strategies, and interface designs have been emerging in very recent years. This review provides essential updates on the important advances in the topic.…”
Section: Introductionmentioning
confidence: 93%
“…The most straightforward and widely utilized approach for creating an air-tight environment involves the use of coin-cell casings with Kapton windows. 100 These cell casings are crafted with aligned openings on both the cell cases and spacers, with the openings on the cases covered by Kapton tape (Fig. 6(A)).…”
Section: Challenges and Advanced Characterization Of All-solid-state ...mentioning
confidence: 99%
“…No destruction, high detection speed, high precision, and no contamination Not applicable to amorphous materials and not suitable for direct observation morphology [28] In situ XPS Elemental composition…”
Section: In Situ Xrd Phase Transition and Structural Changementioning
confidence: 99%
“…(1) In situ XRD spectroscopy X-ray features the particular sensitivity of Bragg diffraction and strong penetration. XRD is an analytical method that uses X-ray diffraction formed by crystals to acquire information such as the morphology or structure of atoms or molecules inside materials and the composition of materials, and is broadly used in the study of the material phase and lattice due to its advantages of no destruction to the sample, high detection speed, high precision, and no contamination [28]. For lithium metal batteries, XRD is frequently utilized to investigate the phase transitions, crystallinity, and crystal structure of solid electrolytes and electrodes.…”
Section: In Situ/operando Characterizationmentioning
confidence: 99%