Recent advances in Fe-based metal–organic framework derivatives for battery applications

Zhang, Yuze; Huang, Qianhong; Liu, Jiawei; Zhou, Jian‐En; Lin, Xiaoming; Zeb, Akif; Reddy, R. Chenna Krishna; Xu, Xuan

doi:10.1039/d2se00319h

Cited by 15 publications

(6 citation statements)

References 162 publications

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“…[34][35][36][37] Some articles only focus on the synthesis strategies and applications of Fe-based MOFderived materials, while neglecting the mechanism analysis of electrocatalysts. 38 As shown in Scheme 2, the discussion in this article is more specific and comprehensive, thus filling the gaps in these aspects. Herein, we briefly introduce the catalytic mechanism of Fe-based MOF-derived electrocatalysts.…”

Section: Ting-feng Yi Ying Xiementioning

confidence: 99%

Advanced design strategies for Fe-based metal–organic framework-derived electrocatalysts toward high-performance Zn–air batteries

Guo,

Zhao,

Zhang

et al. 2024

Energy Environ. Sci.

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Section: Ting-feng Yi Ying Xiementioning

confidence: 99%

Advanced design strategies for Fe-based metal–organic framework-derived electrocatalysts toward high-performance Zn–air batteries

Guo,

Zhao,

Zhang

et al. 2024

Energy Environ. Sci.

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“…Zhang et al reported a simple approach to synthesize porous Fe 2 O 3 by calcining MOF sheets in air [131]. Porous Fe 2 O 3 with a controllable morphology selectively oxidized H 2 S to sulfur.…”

Section: 23mentioning

confidence: 99%

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

Nivetha

Sharma

Jana

et al. 2023

International Journal of Energy Research

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Metal–organic frameworks (MOFs), as a new generation of intrinsically porous extended crystalline materials formed by coordination bonding between the organic ligands and metal ions or clusters, have attracted considerable interest in many applications owing to their high porosity, diverse structures, and controllable chemical structure. Recently, 2D transition-metal- (TM-) based MOFs have become a hot topic in this field because of their high aspect ratio derived from their large lateral size and small thickness, as well as the advantages of MOFs. Moreover, 2D TM-based MOFs can act as good precursors to construct heterostructures with high electrical conductivity and abundant active sites for a range of applications. This review comprehensively introduces the widely adopted synthesis strategies of 2D TM-based MOFs and their composites/derivatives. In addition, this paper summarizes and highlights the recent advances in energy conversion and storage, including the hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, CO2 reduction reaction, urea oxidation reaction, batteries, and supercapacitors. Finally, the challenges in developing these intriguing 2D layered materials and their composites/derivatives are examined, and the possible proposals for future directions to enhance the energy conversion and storage performance are reviewed.

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“…The reactivity and diffusion behavior of an organic ligand with the metal nodes during the process of crystallization can be affected by the surfactant or capping agent that is currently used as an additive to direct the growth of MOFs . The design and synthesis of MOF-derived oxygen electrocatalysts, mono- and multibenzene carboxylates, have been extensively studied. − Zhu et al described well-defined 2D NiFeMOF@NS with the coordination of 1,4-benzenedicarboxylic acid. Further, Niu et al reported that Fe nanoparticles (Fe NPs) encapsulated Fe single atoms.…”

Section: Introductionmentioning

confidence: 99%

3D Hierarchical MOF-Derived Defect-Rich NiFe Spinel Ferrite as a Highly Efficient Electrocatalyst for Oxygen Redox Reactions in Zinc–Air Batteries

Gopalakrishnan,

Kao-ian,

Rittiruam

et al. 2024

ACS Appl. Mater. Interfaces

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The strategy of defect engineering is increasingly recognized for its pivotal role in modulating the electronic structure, thereby significantly improving the electrocatalytic performance of materials. In this study, we present defect-enriched nickel and iron oxides as highly active and cost-effective electrocatalysts, denoted as Ni 0.6 Fe 2.4 O 4 @NC, derived from NiFe-based metal−organic frameworks (MOFs) for oxygen reduction reactions (ORR) and oxygen evolution reactions (OER). XANES and EXAFS confirm that the crystals have a distorted structure and metal vacancies. The cation defect-rich Ni 0.6 Fe 2.4 O 4 @NC electrocatalyst exhibits exceptional ORR and OER activities (ΔE = 0.68 V). Mechanistic pathways of electrochemical reactions are studied by DFT calculations. Furthermore, a rechargeable zinc−air battery (RZAB) using the Ni 0.6 Fe 2.4 O 4 @NC catalyst demonstrates a peak power density of 187 mW cm −2 and remarkable long-term cycling stability. The flexible solid-state ZAB using the Ni 0.6 Fe 2.4 O 4 @NC catalyst exhibits a power density of 66 mW cm −2 . The proposed structural design strategy allows for the rational design of electronic delocalization of cation defect-rich NiFe spinel ferrite attached to ultrathin Ndoped graphitic carbon sheets in order to enhance active site availability and facilitate mass and electron transport.

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Recent advances in Fe-based metal–organic framework derivatives for battery applications

Abstract: Due to the rapid energy consumption and environmental pollution, it has become necessary to develop rechargeable batteries with better electrochemical performance, especially when the traditional rechargeable battery is hard to...

Cited by 15 publications

References 162 publications

Advanced design strategies for Fe-based metal–organic framework-derived electrocatalysts toward high-performance Zn–air batteries

Advanced design strategies for Fe-based metal–organic framework-derived electrocatalysts toward high-performance Zn–air batteries

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

3D Hierarchical MOF-Derived Defect-Rich NiFe Spinel Ferrite as a Highly Efficient Electrocatalyst for Oxygen Redox Reactions in Zinc–Air Batteries

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