This review aims to explore the application of natural and renewable bioceramics such as eggshell and seashells in carbon dioxide (CO 2) capture from power plant flue gas. CO 2 capture, utilisation and storage (CCUS) is considered a means to deliver low carbon energy, decarbonising industries, power plants and facilitates the net removal of CO 2 from the atmosphere. The stages involved include CO 2 capture, transport of the captured CO 2 , utilisation and secure storage of the captured CO 2. This chapter reports the use of eggshell and seashells biomaterials as an adsorbent to separate CO 2 from other gases generated by power plants and industrial processes. The capture of carbon dioxide by adsorption is based on the ability of a material to preferentially adsorb or carbonate CO 2 over other gases. In light of this, calcined eggshell and seashells biomaterial rich in calcium carbonate from which calcium oxide (94%) can be obtained have demonstrated a strong affinity for CO 2. These biomaterials are abundant and low-cost alternative to zeolite, activated carbon and molecular sieve carbon. The mechanism of CO 2 capture by eggshell and seashells derived CaO adsorbent comprises of a series of carbonation-calcination reactions (CCR): calcium oxide (CaO) reacts with CO 2 resulting in calcium carbonate (CaCO 3), which releases pure CO 2 stream upon calcinations for sequestration or utilisation, and as a consequence, the biomaterial is regenerated. Findings reveal that these biomaterials can hold up to eight times its own weight of CO 2 from flue gas stream. It was also found that the combination of 2 M acetic acid and water pretreatment improved the reactivity and capture capacity of the biomaterial for successive regeneration over four cycle's usage. Unlike activated carbon, these biomaterials are considered stable for hightemperature adsorption through carbonation.