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Patai's Chemistry of Functional Groups 2017
DOI: 10.1002/9780470682531.pat0848
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Recent Advances in Acid–Base and Solvation Properties of Metal Phenolates

Abstract: This chapter is an update of a recent review on the acid–base chemistry and solvation properties of metal phenolates. After a brief introduction on the physicochemical properties of metal phenolates, the interaction between phenolate ligands and metal Lewis acids is discussed. Examples of solvent effects on the acid–base properties, structure, and chemical reactivity are presented. Furthermore, the interaction of multidentate phenolic ligands and metal cations is highlighted because of their relevance in trans… Show more

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Cited by 2 publications
(1 citation statement)
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“…In this context, pure phenol metal salts have been reported only for some simple phenols, including phenol and its alkyl derivatives, resorcinol, and some other simple phenols. [34,[42][43][44] Considering the above, the present work demonstrates our initial approach to the conversion of the simple natural bioactive phenolic compound "thymol" into its corresponding metal/ ammonium salts. Various metal (Na, K, Li, Cu, Zn) and ammonium (tetrabutyl ammonium and choline) salts of thymol have been synthesized and characterized using IR, NMR, TGA, CHN and DSC analysis.…”
Section: Introductionmentioning
confidence: 87%
“…In this context, pure phenol metal salts have been reported only for some simple phenols, including phenol and its alkyl derivatives, resorcinol, and some other simple phenols. [34,[42][43][44] Considering the above, the present work demonstrates our initial approach to the conversion of the simple natural bioactive phenolic compound "thymol" into its corresponding metal/ ammonium salts. Various metal (Na, K, Li, Cu, Zn) and ammonium (tetrabutyl ammonium and choline) salts of thymol have been synthesized and characterized using IR, NMR, TGA, CHN and DSC analysis.…”
Section: Introductionmentioning
confidence: 87%