A concise pressure controlled isothermal heating vertical deposition ͑PCIHVD͒ method is developed, which provides an optimal growing condition with better stability and reproducibility for fabricating photonic crystals ͑PCs͒ without the limitation of colloidal sphere materials and sizes. High quality PCs are fabricated with PCIHVD from polystyrene spheres with diameters ranging from 200 nm to 1 m. The deep photonic band gap and steep photonic band edge of the samples are most favorable for realizing ultrafast optical devices, photonic chips, and communications. This method makes a meaningful advance in the quality and diversity of PCs and greatly promotes their wide applications. © 2007 American Institute of Physics. ͓DOI: 10.1063/1.2435613͔Photonic crystals have the properties of confining and controlling the propagation of light due to the existence of photonic band gaps in these periodic dielectric structures.
1,2The unique optical properties make them have wide applications in optical communications, photonic computing, switching, sensing, lasing, and solar cells. [3][4][5][6][7] To realize these utilizations, significant efforts have been devoted to fabricate photonic crystals. [8][9][10][11][12][13][14][15][16][17][18][19] Among them, the colloidal sphere selfassembling provides a simple, cost-efficient approach to fabricate three-dimensional ͑3D͒ photonic crystals ͑PCs͒.
12-19Vertical deposition method, developed by Jiang et al.12 is widely used to form large scale single-crystalline PCs with controllable thickness and superior quality compared to other self-assembly methods. [8][9][10][11][12][13][14][15][16][17][18][19] Recently, some effectively improved approaches based on the vertical deposition method have been developed to break through its two limitations: sedimentation of large colloidal spheres and long evaporation time.20 Vlasov et al. added a vertical temperature gradient to enhance convective flows in sphere dispersions and successfully produced colloidal crystal films with 855 nm silica spheres.21 Kitaev and Ozin et al. 22 applied accelerated evaporation technique to assemble surface patterns of binary colloidal crystals. A great development was made by Wong et al. 20 in their isothermal heating evaporation-induced selfassembly ͑IHEISA͒ method. They successfully assembled high quality colloidal crystal films from 1 m silica spheres in a short time. However, two side effects were yielded due to the fixed high isothermal heating temperature which is slightly above the boiling point of solvent: ͑1͒ the heavy necking of polystyrene ͑PS͒ spheres during deposition, 20 which are widely used to fabricate tunable band gap photonic crystals and the template for inverse opal, and ͑2͒ the nonadjustable solvent evaporation rate. The current issue is that none of the self-assembly methods available is suitable for assembling colloidal spheres of various materials and different sizes. Moreover, the quality of photonic crystals made by these methods cannot meet the practical optical applications yet, w...