Reaktionsverhalten der Kohlenhydrate in wasserfreiem, flüssigem Fluorwasserstoff

Abstract

The present review discusses reactions of unprotected and protected carbohydrates i i~ hydrogen fluoride as well as the synthesie of fluorinated carbohydrates by use of anhydrous liquid hydrogen fluoride or systems containing hydrogen fluoride ( e . g. HFlpyridine, triethylamine trishydrofltwride). Our results concerning the stereoselective synthesis of kinetically controllrd glycosyl fluorides and the micellar aggregation of amphiphitic 3-0-(n-ulky1)-D-gtucopyrunose derivatives in H F are involved. The paper presents a brief introduction in a survey concerning the application of jluorinated carbohydrates. The literuture published since the article of Lenard (190'9) is summarized.