Reaktionskinetik der reversen Wassergas‐Shift‐Reaktion zur Übertragung auf die Synthesegasbereitstellung im PtL‐Prozess

Adelung, Sandra; Schnellbögl, Daniel; Dietrich, Ralph‐Uwe

doi:10.1002/cite.201650370

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2021

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“…Thermodynamic equilibrium is assumed, as has been applied in previous studies [13,38]. In [45], kinetic experiments are conducted using a monolithic, noble metal catalyst at 1.5 bar for different H 2 , CO 2 and CH 4 feeds at different temperatures (600-900 • C) and at a high residence time. The equilibrium composition calculated in Aspen Plus® matches the experimental results, if carbon formation is suppressed in the simulation [45].…”

Section: Validity Of the Process Modelmentioning

confidence: 99%

“…In [45], kinetic experiments are conducted using a monolithic, noble metal catalyst at 1.5 bar for different H 2 , CO 2 and CH 4 feeds at different temperatures (600-900 • C) and at a high residence time. The equilibrium composition calculated in Aspen Plus® matches the experimental results, if carbon formation is suppressed in the simulation [45]. The calculation of the burner temperature is based on empirical data for methane steam reforming.…”

Section: Validity Of the Process Modelmentioning

confidence: 99%

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