Reactivity of the [ReNR]³⁺and [ReN]²⁺cores toward bis(diphenylphosphino)amine and its derivatives. Synthesis and crystal structures

Alkali Metal and Alkaline Earth Metal Complexes with the Bis(borane‐diphenylphosphanyl)amido Ligand – Synthesis, Structures, and Catalysis for Ring‐Opening Polymerization of ϵ‐Caprolactone

“…[11,12] The di-chalcogenoimido-diphosphinto bismuth compounds, Bi[(EPR 2 ) 2 N] 3 (E = S, Se; R = Ph, iPr), were found to be ideal www.zaac.wiley-vch.de ARTICLE for use as single-source precursors as they are air-stable and readily obtainable in good synthetic yields. [13] The diselenoimido-diphosphinato ligand can also stabilize a wide range of metal coordination spheres including alkali metals, [14][15] group 12, [16] group 13, [17,18] group 14, [19,20,16] group 15, [21] group 16, [22,23] transition metals (V and Cr, [24] Mn [25,26] and Re, [27] Ru, Rh, Ir, [15,28,29] Os, [30] Co, [31] group 10: Ni, [32] Pd, [32,[33][34][35] Pt, [14,30,34] and group 11: [35] , and rare earth metals. [36,37] This could be due to the flexible nature of the ligand moieties, which adopt to several metallacyclic rings depending upon the coordination to the central metal atom.…”

Bis(bidentate) complexes of iminobis(diphenylphosphine chalcogenides)[M{N(XPPh2)2-X,X′}2](X = S or Se; M = Ni, Pd or Pt)

“…132,7(t)o in I and 132. 3(2)0 in 1I-J. It is interesting that despite the electronic relationship of acetylacetone and II (which although not isoelectronic are closely related), although Group 10 complexes of acetylacetone all contain planar six-membered rings, here the rings are all puckered.…”

Ionic Platinum(II)–Imidobis(diphenylthiophosphinato) Complexes: Preparation, Structure, and Thermal Behavior

“…Anionic functional ligands of this type are analogues of the more familiar β-diketonate ligands, most notably aceylacetonate (acac). [1][2][3][4] On the other hand, dichalcogenoimidodiphosphinato anions [R 2 P(X)NP(Y)R 2 ] − (R = R = Me, Pr, Ph; X Y O, S, Se) coordinate to the metals forming inorganic (carbon-free) chelate rings. Such chelates are widely used in metal extraction, catalytic, and medicinal applications.…”