Reactivity of osmium–rhodium mixed-metal cluster [Os3Rh(μ-H)3(CO)12] towards vinyl containing ligands

Lau, Jasmine Po-Kwan; Wong, Wing Tak

doi:10.1016/s0022-328x(02)01721-7

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Reactions In the Presence Of Heterometallic Catalysts1

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2014

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Cited by 7 publications

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“…Preliminary experiments showed that in the presence of the hydrido-bridged cluster [Os 3 Rh(μ-H) 3 (CO) 12 ] ( 17 ), isomerization of 1-octene to all isomers was observed at 333 and 373 K, but not at room temperature. The reaction conditions were not optimized …”

Section: Reactions In the Presence Of Heterometallic Catalystsmentioning

confidence: 99%

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

2014

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Section: Reactions In the Presence Of Heterometallic Catalystsmentioning

confidence: 99%

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

2014

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The Molecular Structure of [Os₃Rh₄(μ₃‐η¹:η¹:η¹‐C₆H₅CH₃)(CO)₁₃]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

Lau¹,

Yang²,

Wong³

2003

Angewandte Chemie

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The Molecular Structure of [Os₃Rh₄(μ₃‐η¹:η¹:η¹‐C₆H₅CH₃)(CO)₁₃]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

2003

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Rhodium gets a new flat cap: A novel face‐capping mode of toluene on the title {Os3Rh4} cluster is observed (see structure; Os blue, Rh green, C gray, O red, H white). The cluster is obtained from the reaction of [Os3Rh(μ‐H)3(CO)12] with toluene in the presence of an excess amount of 4‐vinylphenol under reflux for 2 h. The new cluster has relatively short metal–metal bonds and an electron count of only 92, which is four electrons less than expected.

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Reactivity of osmium–rhodium mixed-metal cluster [Os3Rh(μ-H)3(CO)12] towards vinyl containing ligands

Cited by 7 publications

References 15 publications

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

The Molecular Structure of [Os₃Rh₄(μ₃‐η¹:η¹:η¹‐C₆H₅CH₃)(CO)₁₃]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

The Molecular Structure of [Os₃Rh₄(μ₃‐η¹:η¹:η¹‐C₆H₅CH₃)(CO)₁₃]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

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Reactivity of osmium–rhodium mixed-metal cluster [Os3Rh(μ-H)3(CO)12] towards vinyl containing ligands

Cited by 7 publications

References 15 publications

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

The Molecular Structure of [Os3Rh4(μ3‐η1:η1:η1‐C6H5CH3)(CO)13]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

The Molecular Structure of [Os3Rh4(μ3‐η1:η1:η1‐C6H5CH3)(CO)13]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

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The Molecular Structure of [Os₃Rh₄(μ₃‐η¹:η¹:η¹‐C₆H₅CH₃)(CO)₁₃]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

The Molecular Structure of [Os₃Rh₄(μ₃‐η¹:η¹:η¹‐C₆H₅CH₃)(CO)₁₃]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters