Abstract:The radical polymerization of individual stereoisomers of 4-(3-buten-1 -ynyl)-l,2,5-trimethyl-4-piperidinol (1) was investigated. The reaction order with respect to the monomer and the initiator, and also the kinetic and energetic parameters of the polymerization reaction were determined. The values of constants of polymerization of the stereoisomers were found with the help of the "rotating sector" method. It was established that the spatial orientation of the reactive centres with respect to the six-membered… Show more
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