2011
DOI: 10.1016/j.mencom.2011.11.009
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Reactivity of extended chalcogen–nitrogen π-systems: compounds Ar–Se–N=S=N–Se–Ar

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Cited by 5 publications
(2 citation statements)
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“…Organosulfenyl chlorides or selenenyl chlorides are versatile reagents in organic synthesis. They are commonly used to install a chalcogenyl group into various organic substrates, which can be further derivatized. In addition, they have also been widely employed to conduct a large range of synthetic transformations. Because of the significant usefulness of these compounds, many methods for their synthesis have been reported. Among these approaches, the most general methods include passing chlorine gas directly through a solution of thiophenol or disulfide/diselenide, reacting diphenyl disulfide/diselenide with sulfuryl chloride, ,, and chlorinating thiophenol with NCS. ,, It is noteworthy that on many occasions, rather than preparing these organochalcogenyl chloride reagents in advance, protocols utilize in situ formation of such reactive reagents, for example, from the reaction of the corresponding thiol and N -chlorosuccinimide (NCS) ,, or disulfide/diselenide and SO 2 Cl 2 …”
mentioning
confidence: 99%
“…Organosulfenyl chlorides or selenenyl chlorides are versatile reagents in organic synthesis. They are commonly used to install a chalcogenyl group into various organic substrates, which can be further derivatized. In addition, they have also been widely employed to conduct a large range of synthetic transformations. Because of the significant usefulness of these compounds, many methods for their synthesis have been reported. Among these approaches, the most general methods include passing chlorine gas directly through a solution of thiophenol or disulfide/diselenide, reacting diphenyl disulfide/diselenide with sulfuryl chloride, ,, and chlorinating thiophenol with NCS. ,, It is noteworthy that on many occasions, rather than preparing these organochalcogenyl chloride reagents in advance, protocols utilize in situ formation of such reactive reagents, for example, from the reaction of the corresponding thiol and N -chlorosuccinimide (NCS) ,, or disulfide/diselenide and SO 2 Cl 2 …”
mentioning
confidence: 99%
“…21 Related Se-arylselenosulfates (Se-Bunte salts) were obtained via the hydrolysis of Ar–Se–NSN–Se–Ar (Ar = C 6 F 5 , 3-ClC 6 F 4 ). 22…”
Section: Resultsmentioning
confidence: 99%