Reactivity of an Iron Carbonyl Dianion Dictated by a Lewis Basic Appendant
Xiaohu Zhang,
Xueying Guo,
Jiaxiang Chu
Abstract:Studies toward transition metals in negative oxidation states are much less explored compared to those in zero or positive oxidation states. In this study, we present the synthesis and reactivity studies of an Fe(‐II) carbonyl dianion (3) featuring an appended Lewis base, [(L)Fe(CO)3]2‐ (L=Ph2PCH2CH2NMe2). Unlike the well‐known reactivity of [Fe(CO)4]2‐ with common electrophiles (E+) which typically forms [(E)2Fe(CO)4], 3 reacted with 2 equiv. of Ph3SnCl to afford a mixture of two products: one being an Fe(II)… Show more
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