Reactivity and Cross-Reactivity in Redox Activation of the Uranyl Ion
Emily Mikeska,
Malgorzata Makos,
Vassiliki-Alexandra Glezakou
et al.
Abstract:The properties of the uranyl dication (UO22+) are governed in many respects by its redox chemistry, and functionalizing the strong U–O bonds often requires reduction from U(VI) to U(V) with solution-phase multicomponent reaction chemistry that involves both strong reductants and electrophiles. Here, we report the patterns of reactivity and cross-reactivity displayed by a model system in which oxo-activating conditions have been tested that involve either i) electrochemical or chemical reduction, or ii) coordin… Show more
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