Reactive kinetics of carbon dioxide loaded aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol and piperazine using a pressure drop method

Ullah, Sami; Suleman, Humbul; Tahir, Muhammad Suleman; Sagir, Muhammad; Muhammad, Shabbir; Al‐Sehemi, Abdullah G.; Zafar, Masood-ur-Rauf; Kareem, Firas A. Abdul; Maulud, Abdulhalim Shah; Bustam, Mohamad Azmi

doi:10.1002/kin.21252

Cited by 15 publications

(5 citation statements)

References 43 publications

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“…A small amount of PZ is necessary for the reaction to take place, while the addition of AEPD, an SHA, improves the system’s capacity for absorbing CO 2 . Ullah et al also experimentally studied the rate constant of the CO 2 reaction with blended amine absorbent AEPD-PZ with a new pressure drop method and obtained a similar conclusion. By addition of 0.1 mol/L PZ to AEPD, the observed rate constant, k 0 , was determined to be 8824.1 s –1 .…”

Section: Sterically Hindered Amine-based Absorbents: Roles In Co2 Abs...mentioning

confidence: 71%

Recent Progress on CO₂ Capture Based on Sterically Hindered Amines: A Review

Guo,

Li,

Liu

et al. 2023

Energy Fuels

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Excessive greenhouse gas emissions have led to a series of environmental problems, such as the increasing greenhouse effect, rising sea levels, and melting glaciers at the poles, threatening the global environment for human existence. In view of this, the development of CO2 capture technologies with commercialization potential is imperative, as CO2 is the primary contributor to greenhouse gases. In recent years, chemical absorption techniques founded on sterically hindered amines, such as 2-amino-2-methyl-1-propanol (AMP), have garnered escalating interest owing to their benefits of large absorption capacity and diminished energy consumption for regeneration as compared to traditional amine-based methods. In this review, the steric hindrance effect of a sterically hindered amine and its reaction mechanism with CO2 are reviewed. Subsequently, sterically hindered amine absorbents are classified into four kinds, single amine absorbents, blended amine absorbents, biphasic amine absorbents, and nonaqueous amine absorbents, and recent advancements in investigating the kinetic and thermodynamic characteristics of carbon dioxide sequestration through the utilization of sterically hindered amine sorbents are comprehensively evaluated. Technical-economic analysis and life cycle assessment of the CO2 capture processes based on sterically hindered amine absorbents have been comprehensively reviewed. Furthermore, future work for CO2 capture technologies based on sterically hindered amines is suggested.

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Section: Sterically Hindered Amine-based Absorbents: Roles In Co2 Abs...mentioning

confidence: 71%

Recent Progress on CO₂ Capture Based on Sterically Hindered Amines: A Review

Guo,

Li,

Liu

et al. 2023

Energy Fuels

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“…Piperazine (PZ) and its derivatives are commonly used promoters to enhance the CO 2 kinetics and absorption capacity [27][28][29][30]. This study proposes the use of biocatalysts to promote the CO 2 absorption-desorption process.…”

Section: Introductionmentioning

confidence: 99%

Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture

Orhan

2021

Hacettepe Journal of Biology and Chemistry

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S terik engelli amin sisteminin susuz çözeltisinin (2-amino-2-etil-1,3-propandiol (AEPD): 1-hekzanol) ardışık CO 2 absorpsiyon-desorpsiyon performansı gaz-sıvı karıştırmalı hücre reaktöründe incelenmiştir. Farklı AEPD: 1-hekzanol konsantrasyonları için absorpsiyon kapasitesi ve başlangıç absorpsiyon hızı 303 K ve 2 bar mutlak basınçta hesaplanmıştır. AEPD miktarının artırılması CO 2 absorpsiyon kapasitesini arttırmıştır. Sabit miktarda karbonik anhidrazın (CA) CO2 absorpsiyon performansı üzerindeki biyokatalitik etkisi de araştırılmış, ve CA enziminin toplam absorplanan CO 2 miktarını arttırdığı bulunmuştur. AEPD: 1-hekzanol ve CA ile aktifleştirilen AEPD: 1-hekzanolün CO 2 yüklemesi sırasıyla 0.88 ve 0.97 mol CO 2 /mol AEPD bulunmuştur. CO 2 desorpsiyon deneyleri, 363 K ve 1.1 bar mutlak N 2 basıncında aynı deney düzeneğinin farklı diziliminde gerçekleştirilmiştir. Ultrasonik ışınlamanın 0.1 g/L CA katalizli AEPD: 1-hekzanol sisteminin desorpsiyon performansı üzerindeki etkisi de araştırılmıştır. Ultrasonik desteğin desorpsiyon süresini kısalttığı ve desorpsiyon hızını arttırdığı gözlenmiştir. Ayrıca, AEPD:1-Hekzanol sisteminin, CA yokluğunda ve varlığındaki, rejenerasyonun etkinliği, yeniden kullanılabilirliği ve performans kaybı Fourier dönüşümü kızılötesi spektrometresi ile analiz edilmiştir. Anahtar Kelimeler CO 2 yakalama, karbonik anhidraz, FTIR, sterik engelli amin.

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“…1), which is abundant and inexpensive renewable resource. Previously, we found that sterically hindered primary amines (AEPD and AMPD) have a high capacity for CO 2 capture but relatively slow reaction kinetics 26 . It has been studied that the reduced chemical reaction rate could be enhanced by adding highly active amine promoters, such as cyclic polyamines 27 .…”

Section: Introductionmentioning

confidence: 99%

The enhanced enzymatic performance of carbonic anhydrase on the reaction rate between CO₂ and aqueous solutions of sterically hindered amines

Cihan

Orhan

2020

Greenhouse Gases

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The kinetics of the reactions of carbon dioxide (CO 2) with aqueous solutions of two different sterically hindered amines (SHAs), 2-amino-2-ethyl-1,3-propanediol (AEPD) and 2-amino-2-methyl-1,3-propanediol (AMPD), in the presence and absence of carbonic anhydrase (CA) was investigated experimentally using stopped-flow conductimetry. The amine concentration, CA concentration, and temperature were varied within the ranges of 0.1-0.5 kmol•m-3 , 0-125 g•m-3 , and 298-353 K, respectively. Based on pseudo first-order reaction conditions, the intrinsic reaction rate (k o) was obtained according to a modified termolecular reaction mechanism. The obtained results showed that the reaction rate between the SHA solutions (either aqueous AEPD or aqueous AMPD) and CO 2 was enhanced significantly upon adding small amounts of CA as a promoter. Such a result supports the use of the aforementioned solvent system as a candidate for CO 2 capture.

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Reactive kinetics of carbon dioxide loaded aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol and piperazine using a pressure drop method

Cited by 15 publications

References 43 publications

Recent Progress on CO₂ Capture Based on Sterically Hindered Amines: A Review

Recent Progress on CO₂ Capture Based on Sterically Hindered Amines: A Review

Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture

The enhanced enzymatic performance of carbonic anhydrase on the reaction rate between CO₂ and aqueous solutions of sterically hindered amines

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Reactive kinetics of carbon dioxide loaded aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol and piperazine using a pressure drop method

Cited by 15 publications

References 43 publications

Recent Progress on CO2 Capture Based on Sterically Hindered Amines: A Review

Recent Progress on CO2 Capture Based on Sterically Hindered Amines: A Review

Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture

The enhanced enzymatic performance of carbonic anhydrase on the reaction rate between CO2 and aqueous solutions of sterically hindered amines

Contact Info

Product

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About

Recent Progress on CO₂ Capture Based on Sterically Hindered Amines: A Review

Recent Progress on CO₂ Capture Based on Sterically Hindered Amines: A Review

The enhanced enzymatic performance of carbonic anhydrase on the reaction rate between CO₂ and aqueous solutions of sterically hindered amines