2001
DOI: 10.1088/0268-1242/16/6/309
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Reactive ion etching of vertical GaN mesas by the addition of CH4to BCl3/H2/Ar inductively coupled plasma

Abstract: Effects of CH 4 addition on the etched profiles were studied during the BCl 3 /H 2 /Ar inductively coupled plasma reactive ion etching of GaN mesas. It was observed that the sidewall angle increases with the addition of up to 10% CH 4 but then decreases with further addition, resulting in a maximum angle of about 86 • at the optimum condition, while the etch rate continuously decreases. It was proposed that the improved anisotropy is due to the polymer deposition on the surfaces, which reduces the mask erosion… Show more

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Cited by 13 publications
(5 citation statements)
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“…It is believed that initial decrease in the etch rate by CH 4 addition is due to the enhanced formation of polymer layers on the etched surface, which suppresses the etching reaction and protects the sidewall. In fact, the formation of polymer layers by the CH 4 addition has also been repeatedly reported in the previous studies, during the ICP etching of InP, SiC and GaN [7][8][9].…”
Section: Resultssupporting
confidence: 60%
“…It is believed that initial decrease in the etch rate by CH 4 addition is due to the enhanced formation of polymer layers on the etched surface, which suppresses the etching reaction and protects the sidewall. In fact, the formation of polymer layers by the CH 4 addition has also been repeatedly reported in the previous studies, during the ICP etching of InP, SiC and GaN [7][8][9].…”
Section: Resultssupporting
confidence: 60%
“…4,5 Nickel masks have previously been used successfully in chlorine-based ECR etching of GaAs-based systems 6 as well as GaN-based systems. As a result of the relatively strong binding energies of the nitrides, the most suitable etching technologies are those that are capable of high plasma density and ion energies, such as inductively coupled ͑ICP͒ and electron cyclotron resonance ͑ECR͒ plasma sources.…”
Section: Introductionmentioning
confidence: 99%
“…For milder etching with low damage of to the mask edges the addition of gases (N 2 , CH 4 , H 2 , Ar or a mixture of these gases) have been used. In this case etched sidewalls can be significantly improved, since the addition gases remove etching residues and reagents generated during the etching process, however, the etching rate will decrease with the use of additional gases [69]. Certain surface roughness sometimes can be beneficial.…”
Section: Sidewall Roughness and Damagementioning
confidence: 99%