“…Thus oxidative additions to (?75-C5H 5)C o(C O )2, (^5-C5EtM e4)C o(CO ) 2 [1] and (?7:'-CsMe5)C o(C O ) 2 [2] have been studied. In all cases the elimination of a carbonyl-group and the oxidation of Co(I) to C o(III) takes place.…”
The phosphorus pseudohalogens P(CN)3, P(NCO)3 and P(NCS)3 react with (η5-C5Me5)Co(CO)2 to give the complexes (η5-C5Me5)Co(CO)XPX2 (X = CN, NCO, NCS). All the compounds are characterized by elemental analysis, IR. electronic and 1H NMR spectra
“…Thus oxidative additions to (?75-C5H 5)C o(C O )2, (^5-C5EtM e4)C o(CO ) 2 [1] and (?7:'-CsMe5)C o(C O ) 2 [2] have been studied. In all cases the elimination of a carbonyl-group and the oxidation of Co(I) to C o(III) takes place.…”
The phosphorus pseudohalogens P(CN)3, P(NCO)3 and P(NCS)3 react with (η5-C5Me5)Co(CO)2 to give the complexes (η5-C5Me5)Co(CO)XPX2 (X = CN, NCO, NCS). All the compounds are characterized by elemental analysis, IR. electronic and 1H NMR spectra
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