2006
DOI: 10.1007/s11172-006-0435-4
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Reactions of thiols and organic sulfides with hydrogen in the presence of iron powder

Abstract: Previously unknown reduction of thiols to hydrocarbons and H 2 S with hydrogen formed by the interaction of powdered iron with dilute HCl was found.Organic disulfides in a mixture of chlorohydrocarbons are efficient additives to mineral oils that decrease friction and attrition wear of steel surfaces. As a result of the boundary friction they decompose to evolve H 2 S and HCl, respectively, and the mobile hydrogen atom in hydrocar bons reacts with air oxygen to form H 2 O. Therefore, it was of interest to reve… Show more

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