Reactions of sodium tetrahydroborate with alkyl and aryl halides: A new approach to the synthesis of B3H 8 − and B12H 12 2− anions

Bykov, A. Yu.; Мальцева, Н. Н.; Генералова, Н. Б.; Zhizhin, K. Yu.; Кузнецов, Н. Т.

doi:10.1134/s003602361311003x

Cited by 14 publications

(1 citation statement)

References 8 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Me 4 NB 3 H 8 was prepared using a modified procedure of [(n‐C 4 H 9 ) 4 N][B 3 H 8 ], in which Me 4 NCl was used instead of (n‐C 4 H 9 ) 4 NBr to get Me 4 NB 3 H 8 precipitate. The crude product was recrystallized from hot methanol to obtain Me 4 NB 3 H 8 of high purity.…”

Section: Methodsmentioning

confidence: 99%

Electroless Plating of Transition Metal Boride with High Boron Content as Superior HER Electrocatalyst

et al. 2020

View full text Add to dashboard Cite

Facile deposition of transition metal boride (TMB) with high‐boron content as highly efficient hydrogen evolution reaction (HER) electrocatalyst has been realized by a facile one‐step electroless‐plating (EP) method. Boron content of the TMB catalyst shows an appreciable impact on its intrinsic HER activity. NiB/NF electrode with thin amorphous nickel boride (NiB) deposition on nickel foam (NF) required overpotential of only 41.2 mV to deliver a current density of 10 mA cm−2 for HER in 1.0 M KOH alkaline electrolyte. Meanwhile, this kind of electrode also shows satisfied stability which can work at large current density of 1000 mA cm−2 for over 72 h without performance degradation. The advance on the TMB electrode may pave a way to the development of practical electrodes for water splitting.

show abstract

Section: Methodsmentioning

confidence: 99%