1977
DOI: 10.1039/f29777301107
|View full text |Cite
|
Sign up to set email alerts
|

Reactions of phosphorus atoms, P(34S), studied by attenuation of atomic resonance radiation in the vacuum ultraviolet

Abstract: Kinetic studies are described for the reaction of ground state phosphorus atoms, P(3'S+), with a number of different gases. P(34S+) was generated by the repetitive pulsed irradiation of PCl3 in the presence of excess helium buffer gas and monitored photoelectrically in absorption by timeresolved attenuation of atomic resonance radiation in the vacuum ultraviolet at A = 177.50 nm { P [ ~S ( ~P ~) I + P[3p ' (("&)I >. Second-order absolute rate constants are reported for the following reactant gases (R) (k&m3 mo… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

1
21
1

Year Published

1979
1979
2022
2022

Publication Types

Select...
7

Relationship

1
6

Authors

Journals

citations
Cited by 21 publications
(23 citation statements)
references
References 1 publication
1
21
1
Order By: Relevance
“…21 Comparable arguments can be advanced to explain the observed quenching of chemiluminescence if PO! is taken to be the emitter, e.g., the reaction 5 02(X 3 };;) + PO(X 2 II) ---+ P0 2 eA 1 ) + Oep) (9) may compete with the association reaction (1).…”
Section: Formation Of Pomentioning
confidence: 97%
“…21 Comparable arguments can be advanced to explain the observed quenching of chemiluminescence if PO! is taken to be the emitter, e.g., the reaction 5 02(X 3 };;) + PO(X 2 II) ---+ P0 2 eA 1 ) + Oep) (9) may compete with the association reaction (1).…”
Section: Formation Of Pomentioning
confidence: 97%
“…Brought to you by | New York University Bobst Library Technical Services Authenticated Download Date | 6/16/15 12:14 AM Modern physical methods employing flow systems or crossed beam techniques can be applied to polyvalent atoms and have already provided many rate constants for the removal of carbon [ 162 -166 ], silicon [ 167 -172 ], germanium [173 -176], nitrogen [177 -180], phosphorus [181][182][183][184][185][186] and sulfur [187,188] atoms in various reaction systems. The recoil technique can, however, sample a broader energy range than is currently practical for the study of neutral species by physical methods.…”
Section: Polyvalent Atoms and Reactive Intermediatesmentioning
confidence: 99%
“…The reaction between Si and CO 2 is also interesting because of its role in chemical vapor deposition (CVD) process for semiconductor industry as well as for producing new ceramic materials 9. The reaction of Si‐atom with CO 2 at room temperature was first investigated by Hussain and Norris 10 using atomic absorption spectroscopy (AAS) and then the same reaction was studied at high temperature by Mick and Roth 9 using shock tube technique. The Si + CO 2 reaction was explained by a non‐adiabatic transition from the triplet reactant surface to the singlet product surface 10.…”
Section: Introductionmentioning
confidence: 99%
“…The reaction of Si‐atom with CO 2 at room temperature was first investigated by Hussain and Norris 10 using atomic absorption spectroscopy (AAS) and then the same reaction was studied at high temperature by Mick and Roth 9 using shock tube technique. The Si + CO 2 reaction was explained by a non‐adiabatic transition from the triplet reactant surface to the singlet product surface 10. The spin forbidden bimolecular reaction can be represented as follows: …”
Section: Introductionmentioning
confidence: 99%