Reactions of neodymium(II) iodide with organohalides

Fagin, A. A.; Balashova, T. V.; Kusyaev, Dmitrii M.; Kulikova, T. I.; Glukhova, Tatyana A.; Makarenko, N. P.; Kurskii, Yurii A.; Evans, William J.; Bochkarev, M. N.

doi:10.1016/j.poly.2005.08.050

Cited by 15 publications

(8 citation statements)

References 14 publications

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“…Evans, Bochkarev, and co-workers have extended the scope of the reactions of NdI 2 with organohalides (Scheme 30). [87] In THF, NdI 2 promoted the reduction of aryl halides to the corresponding hydrocarbons with minor quantities of products arising from the Wurtz coupling. However, in benzene, a cross-coupling between alkyl chlorides and solvent was observed.…”

Section: Neodymium(ii) Iodidementioning

confidence: 99%

Beyond Samarium Diiodide: Vistas in Reductive Chemistry Mediated by Lanthanides(II)

2012

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Reactions proceeding through open-shell, single-electron pathways offer attractive alternative outcomes to those proceeding through closed-shell, two-electron mechanisms. In this context, samarium diiodide (SmI(2)) has emerged as one of the most important and convenient-to-use electron-transfer reagents available in the laboratory. Recently, significant progress has been made in the reductive chemistry of other divalent lanthanides which for many years had been considered too reactive to be of value to synthetic chemists. Herein, we illustrate how new samarium(II) complexes and nonclassical lanthanide(II) reagents are changing the landscape of modern reductive chemistry.

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Section: Neodymium(ii) Iodidementioning

confidence: 99%

Beyond Samarium Diiodide: Vistas in Reductive Chemistry Mediated by Lanthanides(II)

2012

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“…Solvents were purified by distillation from sodium/benzophenone ketyl (THF and DME) and sodium (hexane). THF for electron spectroscopy was treated with NdI 2 before use [17]. 3,5-Di-tert-butyl-obenzoquinone, 3,5-di-tert-butyl-catechol, Dy, Yb, Tm, Sm, Eu were purchased from Aldrich company.…”

Section: Physical Measurements and Materialsmentioning

confidence: 99%

3,5-Di-tert-butyl-o-benzoquinone complexes of lanthanides

Kuzyaev

Vorozhtsov

Druzhkov

et al. 2012

Journal of Organometallic Chemistry

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“…[87] In THF fçrderte NdI 2 die Reduktion von Arylhalogeniden zu den entsprechenden Kohlenwasserstoffen und geringen Mengen der Produkte einer WurtzKupplung. In Benzol wurde allerdings eine Kreuzkupplung Schema 26.…”

Section: Dysprosium(ii)-iodidunclassified

Jenseits von Samariumdiiodid: Perspektiven für Lanthanoid(II)‐vermittelte Reduktionen

Szostak

Procter

2012

Angewandte Chemie

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Reaktionen, die über offenschalige Einelektronenmechanismen ablaufen, führen zu interessanten alternativen Resultaten gegenüber solchen Reaktionen, die Zweielektronenmechanismen mit geschlossenen Schalen gehorchen. In diesem Zusammenhang entwickelte sich Samariumdiiodid zu einem der wichtigsten Elektronentransferreagentien. In letzter Zeit wurde ein signifikanter Fortschritt auf dem Gebiet der reduktiven Chemie anderer zweiwertiger Lanthanoide erzielt, die viele Jahre lang als zu reaktiv erachtet worden waren, um von Nutzen für Synthesechemiker zu sein. Wir beschreiben hier, wie neue Samarium(II)‐Komplexe und nichtklassische Lanthanoid(II)‐Reagentien die moderne reduktive Chemie verändern.

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Reactions of neodymium(II) iodide with organohalides

Cited by 15 publications

References 14 publications

Beyond Samarium Diiodide: Vistas in Reductive Chemistry Mediated by Lanthanides(II)

Beyond Samarium Diiodide: Vistas in Reductive Chemistry Mediated by Lanthanides(II)

3,5-Di-tert-butyl-o-benzoquinone complexes of lanthanides

Jenseits von Samariumdiiodid: Perspektiven für Lanthanoid(II)‐vermittelte Reduktionen

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