Reactions of N-heterocyclic ligands with substitutionally labile organometallic complexes, [(η5-C5R5)Fe(CO)2E]BF4

M’thiruaine, Cyprian M.; Friedrich, Holger B.; Changamu, Evans O.; Bala, Muhammad D.

doi:10.1016/j.ica.2012.04.003

Cited by 7 publications

(1 citation statement)

References 68 publications

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“…The title compound was prepared according to a reported procedure (M'thiruaine, Friedrich, Changamu & Bala, 2012) and crystals were grown by layering a concentrated solution of the compound in acetone with Et 2 O and the mixture kept undisturbed in the dark for four weeks.…”

Section: S2 Experimentalmentioning

confidence: 99%

Dicarbonyl(η⁵-cyclopentadienyl)(hexamethylenetetramine-κN¹)iron(II) tetrafluoridoborate

2012

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In the structure of the title compound, [Fe(C5H5)(C6H12N4)(CO)2]BF4, the arrangement around the FeII atom corresponds to that of a three-legged piano stool. The cyclopentadienyl ligand occupies three coordination sites of the apical position in a η5 fashion, while two CO ligands and one N atom of the hexamethylenetetramine ligand occupy the remaining coordination sites to complete a distorted octahedral geometry. The asymmetric unit consists of two sets of crystallographically independent cations and anions with the r.m.s. deviations of the overlay of non-H atoms of each pair being 0.081 and 0.120 Å, respectively. The Fe—N bond lengths are 2.0459 (15) and 2.0490 (14) Å, while the Fe—Cp(centroid) distances are 1.7257 (3) and 1.7246 (3) Å. One of the anions displays disorder, with the F atoms having occupancies of 0.58 (4) and 0.42 (4).

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Section: S2 Experimentalmentioning

confidence: 99%

Dicarbonyl(η⁵-cyclopentadienyl)(hexamethylenetetramine-κN¹)iron(II) tetrafluoridoborate

2012

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Syntheses and structural characterization of 2,4,6-trimethylaniline complexes of iron carbonyls

M’thiruaine

Friedrich

Nyawade

et al. 2014

Inorganica Chimica Acta

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Synthesis, characterization and structural elucidation of dicarbonyl(η5-pentamethylcyclopentadienyl)ruthenium(II) complex salts of 1-alkylamines

Nyawade

Friedrich

Omondi

2016

Inorganica Chimica Acta

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Reactions of N-heterocyclic ligands with substitutionally labile organometallic complexes, [(η5-C5R5)Fe(CO)2E]BF4

Cited by 7 publications

References 68 publications

Dicarbonyl(η⁵-cyclopentadienyl)(hexamethylenetetramine-κN¹)iron(II) tetrafluoridoborate

Dicarbonyl(η⁵-cyclopentadienyl)(hexamethylenetetramine-κN¹)iron(II) tetrafluoridoborate

Syntheses and structural characterization of 2,4,6-trimethylaniline complexes of iron carbonyls

Synthesis, characterization and structural elucidation of dicarbonyl(η5-pentamethylcyclopentadienyl)ruthenium(II) complex salts of 1-alkylamines

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Reactions of N-heterocyclic ligands with substitutionally labile organometallic complexes, [(η5-C5R5)Fe(CO)2E]BF4

Cited by 7 publications

References 68 publications

Dicarbonyl(η5-cyclopentadienyl)(hexamethylenetetramine-κN1)iron(II) tetrafluoridoborate

Dicarbonyl(η5-cyclopentadienyl)(hexamethylenetetramine-κN1)iron(II) tetrafluoridoborate

Syntheses and structural characterization of 2,4,6-trimethylaniline complexes of iron carbonyls

Synthesis, characterization and structural elucidation of dicarbonyl(η5-pentamethylcyclopentadienyl)ruthenium(II) complex salts of 1-alkylamines

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Product

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Dicarbonyl(η⁵-cyclopentadienyl)(hexamethylenetetramine-κN¹)iron(II) tetrafluoridoborate

Dicarbonyl(η⁵-cyclopentadienyl)(hexamethylenetetramine-κN¹)iron(II) tetrafluoridoborate