Reactions of chlorotitanium tri-iso-propoxide with methanol and tributylamine

Fric, Helmut; Schubert, Ulrich

doi:10.1007/s10971-008-1706-3

Cited by 4 publications

(2 citation statements)

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“…However it has tin atoms with equal oxidation state, in opposite with our compound, which has different oxidation states and coordination environments of metal atoms. The same situation persists with other compounds of tin and titanium with similar coordination geometry and identical oxidation states of the metal atoms (Eslava et al, 2010;Fric & Schubert, 2008;Harrison et al, 1978;Mijatovic et al, 2001;Mokal et al, 1994;Vatsa et al, 1991;Verdenelli et al, 2000). The title compound has two types of tin atoms.…”

Section: Methodsmentioning

confidence: 56%

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Tetrachloridodi-μ₃-oxido-tetrakis(μ₂-propan-2-olato-κ²O:O)ditin(II)ditin(IV)

et al. 2014

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Key indicators: single-crystal X-ray study; T = 296 K; mean (C-C) = 0.008 Å; R factor = 0.038; wR factor = 0.061; data-to-parameter ratio = 32.7.The centrosymmetric tetranuclear title molecule, [Sn 4 -(C 3 H 7 O) 4 Cl 4 O 2 ], contains two types of Sn atoms, Sn II and Sn IV . The Sn II atom has a trigonal-pyramidal coordination environment and is bonded to two O atoms from two isopropanolate groups and one 3 -oxide atom. The Sn IV atom has an octahedral coordination environment, formed by two chloride atoms, two 3 -oxide atoms and two O atoms from isopropanolate groups. Related literature

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Section: Methodsmentioning

confidence: 56%

“…For the synthesis and structures of related tin and titanium complexes, see: Boyle et al (2002); Eslava et al (2010); Fric & Schubert (2008); Harrison et al (1978); Mijatovic et al (2001); Mokal et al (1994); Vatsa et al (1991); Verdenelli et al (2000).…”

Section: Related Literaturementioning

confidence: 99%