Reactions of benzonitrile with diiodides of neodymium, dysprosium, and thulium

Balashova, T. V.; Kusyaev, D. M.; Еременко, И. Л.; Александров, Г. Г.; Fukin, Georgy K.; Bochkarev, M. N.

doi:10.1023/b:rucb.0000037850.09936.95

Cited by 19 publications

(12 citation statements)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The significant difference in N configurations of TNNs and CTFs-1 suggests that some rearrangement reactions or even decomposition reactions may occur under the synthesis conditions for TNNs. 39,50,51 The atomic ratios of the four N-configurations (N x , x stands for i, ii, iii and iv) in TNNs are further evaluated from the deconvolution of N1s peaks for TNNs (Fig. S10 and Table S2 †), 52,53 and the results are plotted as a function of synthesis temperature in Fig.…”

mentioning

confidence: 99%

Terephthalonitrile-derived nitrogen-rich networks for high performance supercapacitors

Luo

et al. 2012

Energy Environ. Sci.

173

118

View full text Add to dashboard Cite

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.A novel high performance electrode material for supercapacitor applications, terephthalonitrile-derived nitrogen-rich network (TNN), is developed successfully via temperature-dependent cross-linking of terephthalonitrile monomers. This work opens up a new window for seeing a versatile modular toolbox derived from various aromatic nitrile monomers for developing better electrode materials in the future

show abstract

mentioning

confidence: 99%

Terephthalonitrile-derived nitrogen-rich networks for high performance supercapacitors

Luo

et al. 2012

Energy Environ. Sci.

173

118

View full text Add to dashboard Cite

show abstract

“…The use of nitrile as synthetic partner/substrate for the formation of imidazoles has been reported . There are handful of reports to prepare 2,4,5‐trisubstituted imidazoles, but only very limited number of methods are available to make 2 or 4‐acyl substituted imidazoles…”

Section: Introductionmentioning

confidence: 99%

TMSOTf‐Catalysed Synthesis of 2,4,5‐Trisubstituted Imidazoles from Vinyl Azides and Nitriles

et al. 2019

View full text Add to dashboard Cite

TMSOTf‐catalysed generation of 2,4,5‐trisubstituted imidazoles by a simple [3+2] addition reaction of azido chalcones and organic nitriles is described. This transformation generates two new C‐N bonds under mild reaction conditions. The substrate scope of the reaction is excellent with good number of vinyl azides and aromatic and aliphatic nitriles tolerating the reaction. It has been shown that the reaction can also be conducted under microwave condition successfully. These newly synthesized imidazoles are shown to exist as tautomeric mixture and the subsequent methylated as well as benzylated compounds have been obtained as a single regioisomer. The synthesised N‐methyl Imidazole derivative is a potential structural unit towards biologically active compounds.

show abstract

“…This IL was further extended for use with CeBr 3 (THF) 4 , which resulted in a series of polyetherate ligand‐supported CeBr 3 molecules 9. Although the oxophilicity of the lanthanides is well established, we were surprised to find that CeBr 3 (MeCN) 5 · MeCN ( 1 ) was only the second reported example of a monomeric lanthanide(III) halide coordinated solely by nitrile ligands 9,10. However, the Müller‐Buschbaum group has reported a number of examples involving the use of benzonitrile or various substituted bis(cyano)benzene ligands for the synthesis of lanthanide halide coordination polymers 11–14.…”

Section: Introductionmentioning

confidence: 99%