Reaction of pentafluoroethyl radicals with cyanogen chloride

Vöhringer, Cecilia M. de; Staricco, E. H.

doi:10.1039/f19827803493

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1984

1988

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Cited by 4 publications

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“…and R the rate of formation. If the mechanism is accepted and the formation of CF3H through reaction ( 5 ) is not important at low conversion, a is related to the measured ratio [CF3CN]/[CF3H] and could be estimated as (RCF3CN/RCF3W) -1.…”

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confidence: 99%

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The gas-phase reaction of CF₃radicals with HCN in the temperature range 333–523 K

Lane¹,

Oexler²,

Staricco³

1988

J. Chem. Soc., Faraday Trans. 2

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confidence: 99%

“…Similar behaviour was observed for the reactions of C2F5, n-C3F7 and i-C3F7 with C1CN. [5][6][7] We now present results for the reaction of CF3 radicals generated by photolysis of CF,I with HCN in the temperature range 333-523 K.…”

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confidence: 99%

The gas-phase reaction of CF₃radicals with HCN in the temperature range 333–523 K

Lane¹,

Oexler²,

Staricco³

1988

J. Chem. Soc., Faraday Trans. 2

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Hydrogen‐Deuterium Atom Abstraction from Methyl Cyanide by CF₃ Radicals

Pasteris

Oexler

Staricco

1984

Ber Bunsenges Phys Chem

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The reaction of CF3 radicals with CH3CN has been studied over the temperature range 298–623 K, using the photolysis of perfluoroacetic anhydride as a radical source. At temperatures higher than 473 K, the photolysis and the thermal decomposition of CF3I have also been used to generate CF3. — Arrhenius parameters for the reaction were measured relative to the CF3 recombination. The average value of the results from both sources of radicals gave the following parameters The high primary kinetic isotope effect and the non‐curved Arrhenius plot found confirm the absence of an addition reaction.

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Gas phase reactions of CF₃, C₂F₅, and n‐C₃F₇ with carbon tetrachloride

Vöhringer¹,

Staricco²

1984

Int J of Chemical Kinetics

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Reaction of pentafluoroethyl radicals with cyanogen chloride

Abstract: The reaction of C,F, radicals with cyanogen chloride was studied between 293 and 573 K, using perfluoroethyl iodide as the free-radical source. CJ,. The reactions involved areThe main product, C2F,C1, is tormed via an addition reaction or

Cited by 4 publications

References 0 publications

The gas-phase reaction of CF₃radicals with HCN in the temperature range 333–523 K

The gas-phase reaction of CF₃radicals with HCN in the temperature range 333–523 K

Hydrogen‐Deuterium Atom Abstraction from Methyl Cyanide by CF₃ Radicals

Gas phase reactions of CF₃, C₂F₅, and n‐C₃F₇ with carbon tetrachloride

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Reaction of pentafluoroethyl radicals with cyanogen chloride

Abstract: The reaction of C,F, radicals with cyanogen chloride was studied between 293 and 573 K, using perfluoroethyl iodide as the free-radical source. CJ,. The reactions involved areThe main product, C2F,C1, is tormed via an addition reaction or

Cited by 4 publications

References 0 publications

The gas-phase reaction of CF3radicals with HCN in the temperature range 333–523 K

The gas-phase reaction of CF3radicals with HCN in the temperature range 333–523 K

Hydrogen‐Deuterium Atom Abstraction from Methyl Cyanide by CF3 Radicals

Gas phase reactions of CF3, C2F5, and n‐C3F7 with carbon tetrachloride

Contact Info

Product

Resources

About

The gas-phase reaction of CF₃radicals with HCN in the temperature range 333–523 K

The gas-phase reaction of CF₃radicals with HCN in the temperature range 333–523 K

Hydrogen‐Deuterium Atom Abstraction from Methyl Cyanide by CF₃ Radicals

Gas phase reactions of CF₃, C₂F₅, and n‐C₃F₇ with carbon tetrachloride