Reaction of N-[chloro(diorganyl)silyl]anilines with isopropanol and isopropylamine

Abstract

Reaction of N-[chloro(methylvinyl)silyl]-, N-[chloro(methylphenyl)silyl]anilines and of N-[chloro-(methylvinyl)silyl]-, N-[chloro(methylphenyl)silyl]-N-methylanilines with isopropylamine and isopropanolyielding the products of chlorine substitution with isopropoxy and isopropylamino group, respectively, has been studied. Structure of new polyfunctional silanes has been confirmed by IR and NMR spectroscopy.

Atomic-level organization of vicinal acid–base pairs through the chemisorption of aniline and derivatives onto mesoporous SBA15

“…According to the literature the former is attributed to both [( Si O) 3 Si OE], with E = Si or H (commonly dubbed Q 4 and Q 3 ) 50 , 51 and the latter is assigned to the [ Si NHPh]. 52 …”