1998
DOI: 10.1006/jcis.1998.5462
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Reaction of Long-Chain Iodoalkanes with Gold Surfaces

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Cited by 21 publications
(37 citation statements)
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References 25 publications
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“…Given TEM evidence for Ag 0 nanoparticles, it is plausible that the Ag-S-r species (where S is the thiol functional group and r is the organic chain tethered to SiO 2 ) records Ag atoms at the surface of the Ag 0 particles that interact with thiol groups. The component at 369.1 eV is consistent with an Ag-organic species 33,34 and may represent Ag ions trapped in the organic matrix. Alternatively, given the strong dependence of Ag3d binding energy on the size of silver nano-particles, where smaller size yields higher Ag3d BEs, 35 results suggest that there is a reservoir of Ag 0 particles/ clusters at <2 nm that could grade into individual Ag atoms/ ions.…”
Section: Effect Of Aging Investigated With Xpsmentioning
confidence: 76%
“…Given TEM evidence for Ag 0 nanoparticles, it is plausible that the Ag-S-r species (where S is the thiol functional group and r is the organic chain tethered to SiO 2 ) records Ag atoms at the surface of the Ag 0 particles that interact with thiol groups. The component at 369.1 eV is consistent with an Ag-organic species 33,34 and may represent Ag ions trapped in the organic matrix. Alternatively, given the strong dependence of Ag3d binding energy on the size of silver nano-particles, where smaller size yields higher Ag3d BEs, 35 results suggest that there is a reservoir of Ag 0 particles/ clusters at <2 nm that could grade into individual Ag atoms/ ions.…”
Section: Effect Of Aging Investigated With Xpsmentioning
confidence: 76%
“…30 ml of solvent, and dried in an argon stream. (Additional examples, not discussed here, are described in a patent (19)). …”
Section: Methodsmentioning
confidence: 96%
“…The maximum adsorption capacity of 0•81 mg/g were reached in sorbent's dose range of 15-20 g/L that further decreases with increasing sorbent dose as may be due to specific surface adsorption phenomenon. At low sorbent dose all the active sites of sorbent get utilized completely and effectively resulting in high lead adsorption capacity, on the contrary increasing sorbent dose while maintaining lead concentration steady escorts to surplus of adsorbent sites (Hirayama et al 1998;Meghat Hanafiah et al 2007). 3.5d Effect of initial lead concentration: The amount of lead (II) distribution amongst sorbent and solution at equilibrium is vital in determining maximum lead adsorption capacity of adsorbent.…”
Section: 5c Effect Of 30% (W/v) Bromine Pretreated Chitosan Dosementioning
confidence: 99%