Reaction Kinetics of Carbon Dioxide with Phenyl Glycidyl Ether by TEA-CP-MS41 Catalyst

Abstract

CP-MS41 was synthesized by hydrolysis of tetraorthosilicate, as a silicon source, with 3-chloropropyltriethoxysilane as an organosilane using cetyltrimethylammonium bromide as a template. TEA-CP-MS41 was synthesized by immobilization of triethylamine on the mesoporous MCM-41 and was dispersed in organic liquid as a mesoporous catalyst for the reaction between carbon dioxide and phenyl glycidyl ether (PGE). Carbon dioxide was absorbed into the PGE solution in a stirred batch tank with a planar gas-liquid interface within a range of 0-2.0 kmol/m 3 of PGE and 333-363 K at 101.3 kPa. The measured values of absorption rate were analyzed to obtain the reaction kinetics using the mass transfer mechanism associated with the chemical reactions based on the film theory. The overall reaction of CO2 with phenyl glycidyl ether (PGE), which is assumed to consist of two steps: (i) A reversible reaction between PGE (B) and catalyst of TEA-CP-MS41 (QX) to form an intermediate complex (C1), and (ii) irreversible reaction between C1 and CO2 to form QX and five-membered cyclic carbonate (C), was used to obtain the reaction kinetics through the pseudo-first-order reaction model. Polar solvents such as N, N-dimethylacetamide, N-methyl-2-pyrrolidinone, and dimethyl sulfoxide affected the reaction rate constants.

Theoretical Analysis on Absorption of Carbon Dioxide (CO2) into Solutions of Phenyl Glycidyl Ether (PGE) Using Nonlinear Autoregressive Exogenous Neural Networks

“…Carbon dioxide is a generally useful gas made up of a carbon and two oxygen atoms. It is essential in plant photosynthesis, manufacturing carbonated soft drinks, powering pneumatic systems in robots, fire extinguishers, removing caffeine from coffee [ 1 , 2 ], etc. Carbon dioxide has the potential to be a significant and inexpensive carbon source.…”