2015
DOI: 10.1016/j.ijrmhm.2014.07.040
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Reaction chemistry in the Mg–B2O3–MoO3 system reactive mixtures

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Cited by 17 publications
(14 citation statements)
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“…No tangible change is observed in the XRD pattern of sample milled for 2.8 h, suggesting that no new phases were formed. The absence of graphite and boron oxide peaks in this sample could be attributed to transformation of crystal state of these phases into the amorphous state as reported in some investigations [18,19]. After 3 h milling, the peaks of as-blended materials disappear completely; meanwhile, new peaks appear to emerge, corresponding to the formation of MgO (JCPDS: 00-004-0829) and NbB 2 (JCPDS: 00-008-0120).…”
Section: Thermal Analysis and Effect Of Milling Processsupporting
confidence: 72%
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“…No tangible change is observed in the XRD pattern of sample milled for 2.8 h, suggesting that no new phases were formed. The absence of graphite and boron oxide peaks in this sample could be attributed to transformation of crystal state of these phases into the amorphous state as reported in some investigations [18,19]. After 3 h milling, the peaks of as-blended materials disappear completely; meanwhile, new peaks appear to emerge, corresponding to the formation of MgO (JCPDS: 00-004-0829) and NbB 2 (JCPDS: 00-008-0120).…”
Section: Thermal Analysis and Effect Of Milling Processsupporting
confidence: 72%
“…Thus, the first exothermic peak at 820 1C is attributed to the initiation of B 2 O 3 reduction by Mg (magnesiothermic reaction) according to reaction (3). Taking into account the results obtained hitherto in the combustion reaction of Mg-B 2 O 3 -C and Mg-B 2 O 3 -MoO 2 systems [18][19][20][21] as well, the magnesiothermic reduction of B 2 O 3 was occurred at about 800-850 1C. The presence of unreacted Mg peaks indicates that magnesiothermic reaction does not completely occurred during the thermal process.…”
Section: Thermal Analysis and Effect Of Milling Processmentioning
confidence: 93%
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