Rationally Engineered Ultrastable Three-Dimensional (3D) Conjugated Microporous Polymers Containing Triptycene, Tetraphenylethene, and Benzothiadiazole Units as Exceptional High-Performance Organic Electrodes for Supercapacitors

Facile synthesis of anthranilic acid based dual functionalized novel hyper cross-linked polymer for promising CO2 capture and efficient Cr3+ adsorption

“…The thick paste like appearance indicates the syntheses of HCP-AA which was washed with ethanol till pure HCP-AA was obtained after the removal of excessive solvent and FeCl 3 (washed until brown color of FeCl 3 disappeared). After filtrations, purified product was collected in china dish and dried at 100 °C in an oven 57,58 .…”

Reticular design and alkyne bridge engineering in donor–π–acceptor type conjugated microporous polymers for boosting photocatalytic hydrogen evolution

“…[47][48][49][50][51][52][53][54][55][56][57][58][59][60] CMPs could be synthesized using various methods such as Schiff base condensation, Suzuki-Miyaura, Sonogashira, Heck coupling processes, mechanochemical synthesis, solvothermal or hydrothermal methods, microwaveassisted synthesis, and more, all of which are both economically viable and user-friendly. 54,57,[61][62][63][64][65][66][67][68][69] Various monomers featuring diverse functional groups, including aldehydes, amines, and halides, can be employed in the synthesis of CMPs. Notably, CMPs exhibit exceptional chemical and physical stability.…”

Fabrication of Phosphorus- and Nitrogen-Rich Inorganic–Organic Hybrid Hyper-Cross-Linked Polymers for CO2 and I2 Uptake

“…The potential of porous materials for extraordinary sorption capacity of CO 2 and I 2 , established them as the most suitable solid materials to physically adsorb CO 2 and I 2 . − Many types of microporous materials have been fabricated so far such as inorganic–organic hybrid porous materials, microporous organic polymers, polymers of intrinsic microporosity, covalent organic frameworks, crystalline triazine-based frameworks, hyper-cross-linked polymers (HCPs), and porous aromatic frameworks. ,, Recently, inorganic–organic hybrid porous materials (HPMs) have pulled much attention owing to their low density, mechanical and thermal stability, and especially good surface area with tunable porosity as promising materials for gas sorption and isolation, catalysis, environment, and drug delivery applications. , It was revealed that the inorganic part provides structural order, thermal stability, and mechanical strength, and the organic part represents good porosity with tunable functionality. However, the challenge lays in fabrication of materials whose porosities remain intact with a sound compactness in structure compatible to a minimum volume with small surface area.…”