Rational Design of Hierarchical Mn-Doped Na5V12O32 Nanorods with Low Crystallinity as Advanced Cathodes for Aqueous Zinc Ion Batteries

Kong, Xiangzhong; Luo, Shi; Rong, Liya; Wan, Zhongmin; Li, Shi

doi:10.1021/acs.energyfuels.1c02103

Cited by 8 publications

(4 citation statements)

References 36 publications

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“…Third, oxygen vacancies can enhance the redox activity and cycling reversibility of the MnVO electrode and reduce the occurrence of irreversible side reactions, thereby achieving excellent reversible specific capacity, rate, and cycling performance. Compared with the reported vanadium-based oxide in ZIBs, MnVO nanoribbons also exhibit superior reversible specific capacity, high rate performance, and excellent cycling performance at high current density, such as K 0.23 V 2 O 5 , V 2 O 3 @AC, V 2 O 5 , VO 2 -5@ppy, VO 2 (A), and Na 5 V 12 O 32 , which are listed in Figure S6.…”

Section: Resultsmentioning

confidence: 99%

Structural Engineering of Vanadium Oxide Cathodes by Mn²⁺ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries

Sheng

et al. 2023

ACS Appl. Energy Mater.

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Aqueous zinc-ion batteries (ZIBs) have attracted much attention because of their high theoretical capacity and inherent safety. An essential requirement is to design robust cathodes to match the excellent electrochemical properties of zinc anodes. Herein, we report a facile strategy that designed an intercalation-type cathode by incorporating interlayer engineering of Mn 2+ and oxygen defects into tunnel-type VO 2 nanoribbons. The embedded Mn 2+ ions act as pillars to extend the tunnel structure of VO 2 with an improved fast and reversible intercalation/ deintercalation of Zn 2+ in the ZIBs, enhancing electrical conductivity and improving redox activity. In addition, oxygen vacancies in the MnVO nanoribbons can provide extra electrochemically active sites for Zn 2+ storage. As a result, the MnVO electrode delivers an excellent capacity of 462.5 mA h g −1 at 0.1 A g −1 , an outstanding rate performance (120 mA h g −1 at 5 A g −1 after 2500 cycles), and ultralong cycling at 10 A g −1 with a remaining capacity of 52 mA h g −1 over 10,000 cycles. Therefore, this work provides an enlightened strategy for a superior vanadium-based oxide cathode toward the advanced electrochemical performance of ZIBs.

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Section: Resultsmentioning

confidence: 99%

Structural Engineering of Vanadium Oxide Cathodes by Mn²⁺ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries

Sheng

et al. 2023

ACS Appl. Energy Mater.

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“…The accelerated electron and Zn 2+ transportation resulted in outstanding electrochemical with the capacity of 427.3 mAh g −1 at 0.1 A g −1 and 178.2 mAh g −1 at 10 A g −1 . In addition, the formation energy of V MgV 2 O 4 ions doping solvothermal reaction 272 @ 0.2 128.9 @ 4 ≈75% (500) [137] (NH 4 ) 2 V 10 O 25 8H 2 O ions doping hydrothermal reaction 398 @ 0.5 161 @ 5 65% (10 000) [138] Mn-doped Na 5 V 12 O 32 ions doping hydrothermal reaction 365 @ 0.5 315 @ 5 65% (10 000) [139] at 20 A g −1 (Figure 10d). Oxygen vacancies could also be introduced into V 2 O 5 via a thermal reduction by H 2 generated by NaBH 4 .…”

Section: Omentioning

confidence: 99%

Advances on Defect Engineering of Vanadium‐Based Compounds for High‐Energy Aqueous Zinc–Ion Batteries

Guo

et al. 2022

Advanced Energy Materials

115

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However, the organic electrolytes used in LIBs are highly toxic and flammable, and are deemed safety hazards. The limited resources and high-cost of lithium and harsh assemble conditions of LIB cells also hinder the application of LIBs in large-scale energy storage systems. [2] P. Rüetschi proposed the '3 E' criteria including Energy, Economics, and Environment to determine whether the battery system was practical for daily use. [3] Aqueous electrolytes with low price, high safety, and high conductivity can drastically reduce the production cost and improve battery safety. [4] Aqueous zincion batteries (ZIBs) use Zinc as an environment-friendly anode which shows low redox potential (−0.78 eV vs SHE), high electronic conductivity as well as large capacity (820 mAh g −1 and 5851 mAh cm −3 ). [5,6] Therefore, ZIBs are considered as one of the most competitive and promising development directions for next-generation large-scale energy storage. As the initial work in mild aqueous electrolyte, an aqueous ZIB with MnO 2 cathode and Zn anode was reported by Kang and co-workers in 2012. [7] Since then, research interests in ZIBs area develops burgeoningly and more than 1000 research papers about electrode materials on aqueous ZIBs were published.The commonly reported cathode materials are V-based compounds, [8,9] manganese oxides, [10,11] Prussian blue analogs, [12,13] metal chalcogenides, [14,15] and organic compounds. [16,17] Among them, manganese oxides have moderate operating potential and high theoretical capacity, but suffer from manganese dissolution in aqueous electrolytes due to Jahn-Teller dissolution of Mn 3+ , which leads to structural collapse and poor cycling stability. [10,11] Prussian blue analogs often process high operating potential beyond 1.5 V and their open cage-like framework guarantees structure stability under rapid Zn 2+ transmission, leading to good rate performance and long-cycle capacity retention. However, the large framework structures also bring limited theoretical capacity and suffer from O 2 evolution due to the high operating potential. [13,18] Organic cathodes process passable theoretical capacity, high structural diversity, and flexibility, bringing potential prospects in flexible electrodes. But the high dissolubility in electrolytes and high resistance are two bumps to overcome for organic cathodes used in ZIBs. [16,17] V-based compounds have received extensive attention as cathode for ZIBs due to the rich reserves and diversity of valences of vanadium as well as their general high theoretical capacity and Aqueous zinc-ion batteries (ZIBs) have been promptly developed as a competitive and promising system for future large-scale energy storage. In recent years, vanadium (V)-based compounds, with diversity of valences and high electrochemical-activity, have been widely studied as cathodes for aqueous ZIBs because of their rich reserves and high theoretical capacity. However, the stubborn issues including low conductivity and sluggish kinetics, plague their smooth application in aqueous...

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“…The cycling performance of ZIBs is determined by the transfer rate of Zn 2+ ions and the stable electrochemical reaction at electrode/electrolyte interfaces. − Due to the limitations of the parasitic reaction of the zinc metal anode and the dissolution of the cathode material, the capacity of ZIBs decreases rapidly. − Generally, ZIBs exhibit different working mechanisms in different electrolyte environments. In alkaline electrolytes, the (dis)charge reactions mainly involve the insertion and extraction of H + ions. − In neutral/weakly acidic electrolytes, the (dis)charge carriers are the coinsertion of Zn 2+ and H + ions. − Although ZIBs shown higher energy density in alkaline electrolytes, the excessive generation of ZnO and Zn(OH) 4 ‑2 would reduce the reversibility of the Zn metal anode. Besides, the stable plating/stripping of Zn 2+ ions at the solid (electrode)/liquid (electrolyte) interface is crucial for the long-term cycling of ZIBs.…”

Section: Introductionmentioning

confidence: 99%

Electrolyte Additive Strategies for Safe and High-Performance Aqueous Zinc-Ion Batteries: A Mini-Review

Zhang,

Miao,

Song

et al. 2024

Energy Fuels

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With outstanding safety and economic benefits, aqueous zinc-ion batteries (ZIBs) represent a highly promising energy system. As the "blood" of ZIBs, the solid (electrode)/liquid (electrolyte) interface reactions and the transport rate of zinc ions in the electrolyte are crucial fields for long-term ZIBs. However, parasitic reactions and dendrite growth at the electrode/electrolyte interface hinder the practical application of ZIBs. Thus, adjusting the composition of the electrolyte is valuable to reduce active-H 2 O molecules in the solvation structure and realize a textured zinc anode. In this mini-review, the electrochemical reaction dilemmas in electrode/electrolyte interfaces and the modification mechanism of additives are first summarized. Furthermore, we compare the charge transfer and storage methods among various electrolyte additives. Notably, the effects of plating/stripping textures ((100), ( 101) and (002) crystal planes) on the reversibility of zinc metal anodes are highlighted, providing a more intuitive strategy for the epitaxial growth of zinc metal. Finally, the specific applications and perspectives of ZIBs with additives are outlined to guide nextgeneration efficient energy storage.

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Rational Design of Hierarchical Mn-Doped Na₅V₁₂O₃₂ Nanorods with Low Crystallinity as Advanced Cathodes for Aqueous Zinc Ion Batteries

Cited by 8 publications

References 36 publications

Structural Engineering of Vanadium Oxide Cathodes by Mn²⁺ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries

Structural Engineering of Vanadium Oxide Cathodes by Mn²⁺ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries

Advances on Defect Engineering of Vanadium‐Based Compounds for High‐Energy Aqueous Zinc–Ion Batteries

Electrolyte Additive Strategies for Safe and High-Performance Aqueous Zinc-Ion Batteries: A Mini-Review

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Rational Design of Hierarchical Mn-Doped Na5V12O32 Nanorods with Low Crystallinity as Advanced Cathodes for Aqueous Zinc Ion Batteries

Cited by 8 publications

References 36 publications

Structural Engineering of Vanadium Oxide Cathodes by Mn2+ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries

Structural Engineering of Vanadium Oxide Cathodes by Mn2+ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries

Advances on Defect Engineering of Vanadium‐Based Compounds for High‐Energy Aqueous Zinc–Ion Batteries

Electrolyte Additive Strategies for Safe and High-Performance Aqueous Zinc-Ion Batteries: A Mini-Review

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Rational Design of Hierarchical Mn-Doped Na₅V₁₂O₃₂ Nanorods with Low Crystallinity as Advanced Cathodes for Aqueous Zinc Ion Batteries

Structural Engineering of Vanadium Oxide Cathodes by Mn²⁺ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries

Structural Engineering of Vanadium Oxide Cathodes by Mn²⁺ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries