Raspberry-like particles via the heterocoagulated reaction between reactive epoxy and amino groups

Song, Tao; Liu, Tuanwei; Yang, Xinlin; Bai, Feng

doi:10.1016/j.colsurfa.2015.01.016

Cited by 18 publications

(15 citation statements)

References 35 publications

(45 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…As examples for SP‐based coatings, raspberry‐like silica–poly(divinylbenzene‐ co ‐glycidylmethacrylate) SPs were developed for superhydrophobic coatings, [ 184 ] poly(ethyl methacrylate)‐silica ones for antifouling coatings, [ 185 ] hollow silica [ 186 ] ( Figure a), and polystyrene‐silica [ 180 ] (Figure 9b) ones for antifogging coatings, as well as polystyrene ones for superamphiphobic coatings [ 181 ] (Figure 9c).…”

Section: Supraparticles For Sustainabilitymentioning

confidence: 99%

Supraparticles for Sustainability

Wintzheimer

Reichstein

Groppe

et al. 2021

Adv Funct Materials

View full text Add to dashboard Cite

The indispensable transformation to a (more) sustainable human society on this planet heavily relies on innovative technologies and advanced materials. The merits of nanoparticles (NPs) in this context are demonstrated widely during the last decades. Yet, it is believed that the impact of particle‐based nanomaterials to sustainability can be even further enhanced: taking NPs as building blocks enables the creation of more complex entities, so‐called supraparticles (SPs). Due to their evolving phenomena coupling, emergence, and colocalization, SPs enable completely new material functionalities. These new functionalities in SPs can be utilized to render six fields, essential to human life as it is conceived, more sustainable. These fields, selected based on an entropy‐rate‐related definition of sustainability, are as follows: 1) purification technologies and 2) agricultural delivery systems secure humans “fundamental needs.” 3) Energy storage and conversion, as well as 4) catalysis enable the “basic comfort.” 5) Extending materials lifetime and 6) bringing materials back in use ensure sustaining “modern life comfort.” In this review article, a perspective is provided on why and how the properties of SPs, and not simply properties of individual NPs or conventional bulk materials, may grant attractive alternative pathways in these fields.

show abstract

Section: Supraparticles For Sustainabilitymentioning

confidence: 99%

Supraparticles for Sustainability

Wintzheimer

Reichstein

Groppe

et al. 2021

Adv Funct Materials

View full text Add to dashboard Cite

show abstract

“…where ݇ , ݇ ௩ and ݇ ௗ ଶ are the adjustable parameters of the model and ܶ is calculated by means of equation 19.…”

Section: Balances Of Equilibrium and Non-equilibrium Clustersmentioning

confidence: 99%

“…[12] The performance of the composite latex particles is directly affected by their morphology and due to its practical importance, particle morphology has received a considerable attention in the literature. [13][14][15][16][17][18][19][20][21][22][23][24][25][26] Several authors reported theoretical approaches aimed at predicting the particle morphology, but most of the methods are based on two limiting assumptions: either the polymer chains do not move from the point that they are formed [25,[27][28][29][30][31] or the equilibrium morphology is attained instantaneously. [11,[32][33][34][35][36][37][38][39][40] There are only few works in the literature that take into account all relevant kinetic and thermodynamic effects.…”

Section: Introductionmentioning

confidence: 99%

A new approach for mathematical modeling of the dynamic development of particle morphology

Hamzehlou

Leiza

Asúa

2016

Chemical Engineering Journal

View full text Add to dashboard Cite

Please cite this article as: S. Hamzehlou, J.R. Leiza, J.M. Asua, A new approach for mathematical modelling of the dynamic development of particle morphology, Chemical Engineering Journal (2016), doi: http://dx. AbstractA new model for the dynamic evolution of the morphology of polymer-polymer latex particles has been developed. This model overcomes the limitations of the existing methodologies that were only able to provide the morphology of a single particle, which is only a restricted view of the real system that contains a distribution of particle morphologies. Taking into account the relevant kinetic and thermodynamic effects, the new model calculates the distribution of morphologies for the whole population of polymer particles with less computational effort than that needed by the previous models to calculate the morphology of a single particle. The model was validated by fitting the evolution of particle morphology of composite particles during polymerization of methyl methacrylate on a polystyrene seed. Furthermore, the ability of the model to predict the evolution of the particle morphology for different cases was explored.

show abstract

“…The particles they obtained were further used as templates in the preparation of electrostatically stabilized silica‐coated hybrid colloids. Song et al synthesized core corona particles with a raspberry‐like structure through reaction between epoxy and amino groups. The nonspherical particles were deployed for super‐hydrophobic applications.…”

Section: Introductionmentioning

confidence: 99%

Preparation of Nonspherical Fluorinated Acrylate Polymer Particles by a “Surface Tension Controlling” Method and Their Applications in Light‐Diffusing Films

et al. 2019

Macro Materials & Eng

View full text Add to dashboard Cite

A facile “surface tension controlling” method is proposed for the preparation of nonspherical fluorinated acrylate polymer particles (FANPPs) with four different morphologies by adjusting the compositions of polystyrene (PS) cores and monomers in shell layers. The FANPPs are fabricated through an inexpensive and template‐free emulsion polymerization process that allows control of their morphologies. Scanning electronic microscopy, the Wilhelmy plate method, and differential scanning calorimetry are applied to investigate the structures and properties of the FANPPs. The formation mechanism of these unique morphologies is rationalized in terms of a selective wetting process, whereby surface tension and incompatibility between the PS cores and fluorinated shell layers are modified. These novel nanoparticles are first applied to fabricate light‐diffusing films that show both high transmittance and high haze value. The light‐diffusing properties are tested by means of a haze meter. The nonspherical structure of the FANPPs greatly influences their light‐diffusing properties.

show abstract

Raspberry-like particles via the heterocoagulated reaction between reactive epoxy and amino groups

Cited by 18 publications

References 35 publications

Supraparticles for Sustainability

Supraparticles for Sustainability

A new approach for mathematical modeling of the dynamic development of particle morphology

Preparation of Nonspherical Fluorinated Acrylate Polymer Particles by a “Surface Tension Controlling” Method and Their Applications in Light‐Diffusing Films

Contact Info

Product

Resources

About