Abstract:Intercalation of Au can produce giant Rashba-type spin-orbit splittings in graphene but this has not yet been achieved on a semiconductor substrate. For graphene/SiC(0001), Au intercalation yields two phases with different doping. Here, we report the preparation of an almost pure p-type graphene phase after Au intercalation. We observe a 100 meV Rashba-type spin-orbit splitting at 0.9 eV binding energy. We show that this giant splitting is due to hybridization and much more limited in energy and momentum space… Show more
“…No π * band is observed. These observations are reminiscent of others made with related systems [15,17,18,50,21,22], and suggest that graphene here has a freestanding character. In contrast, ARPES measurements on graphene/Re(0001) in the absence of the Au intercalant suggest strong electron donation from the substrate to graphene and hybridization between the C and Re orbitals (figure S1(d)), consistent with previous reports [15,16].…”
Section: Dirac Cone Of Quasi Free-standing Graphenesupporting
Graphene holds promises for exploring exotic superconductivity with Dirac-like fermions. Making graphene a superconductor at large scales is however a long-lasting challenge. A possible solution relies on epitaxially-grown graphene, using a superconducting substrate. Such substrates are scarce, and usually destroy the Dirac character of the electronic band structure. Using electron diffraction (reflection high-energy, and low-energy), scanning tunneling microscopy and spectroscopy, atomic force microscopy, angle-resolved photoemission spectroscopy, Raman spectroscopy, and density functional theory calculations, we introduce a strategy to induce superconductivity in epitaxial graphene via a remote proximity effect, from the rhenium substrate through an intercalated gold layer. Weak graphene-Au interaction, contrasting with the strong undesired graphene-Re interaction, is demonstrated by a reduced graphene corrugation, an increased distance between graphene and the underlying metal, a linear electronic dispersion and a characteristic vibrational signature, both latter features revealing also a slight p doping of graphene. We also reveal that the main shortcoming of the intercalation approach to proximity superconductivity is the creation of a high density of point defects in graphene (10 14 cm −2 ). Finally, we demonstrate remote proximity superconductivity in graphene/Au/Re(0001), at low temperature.
“…No π * band is observed. These observations are reminiscent of others made with related systems [15,17,18,50,21,22], and suggest that graphene here has a freestanding character. In contrast, ARPES measurements on graphene/Re(0001) in the absence of the Au intercalant suggest strong electron donation from the substrate to graphene and hybridization between the C and Re orbitals (figure S1(d)), consistent with previous reports [15,16].…”
Section: Dirac Cone Of Quasi Free-standing Graphenesupporting
Graphene holds promises for exploring exotic superconductivity with Dirac-like fermions. Making graphene a superconductor at large scales is however a long-lasting challenge. A possible solution relies on epitaxially-grown graphene, using a superconducting substrate. Such substrates are scarce, and usually destroy the Dirac character of the electronic band structure. Using electron diffraction (reflection high-energy, and low-energy), scanning tunneling microscopy and spectroscopy, atomic force microscopy, angle-resolved photoemission spectroscopy, Raman spectroscopy, and density functional theory calculations, we introduce a strategy to induce superconductivity in epitaxial graphene via a remote proximity effect, from the rhenium substrate through an intercalated gold layer. Weak graphene-Au interaction, contrasting with the strong undesired graphene-Re interaction, is demonstrated by a reduced graphene corrugation, an increased distance between graphene and the underlying metal, a linear electronic dispersion and a characteristic vibrational signature, both latter features revealing also a slight p doping of graphene. We also reveal that the main shortcoming of the intercalation approach to proximity superconductivity is the creation of a high density of point defects in graphene (10 14 cm −2 ). Finally, we demonstrate remote proximity superconductivity in graphene/Au/Re(0001), at low temperature.
“…We as well observe the Rashba splitting at about −1 eV due to the interaction between the graphene and gold bands, as reported in ref. 33 .…”
Section: Resultsmentioning
confidence: 99%
“…The effects reported were doping of the graphene π-bands 30,31 or mini-gaps opening in the graphene Dirac cone due to moiré superperiodicity 32 . It was recently shown that the interaction between the 5d orbitals of gold and the valence band of graphene can open a spin-orbit gap deep in the valence band of goldintercalated graphene on SiC(0001) 33 . However, no evidence of two-dimensional dispersing bands stemming from the metal layer was ever reported, which would be indicative of a well-defined order of the film.…”
The synthesis of two-dimensional (2D) transition metals has attracted growing attention for both fundamental and application-oriented investigations, such as 2D magnetism, nanoplasmonics and non-linear optics. However, the large-area synthesis of this class of materials in a single-layer form poses non-trivial difficulties. Here we present the synthesis of a largearea 2D gold layer, stabilized in between silicon carbide and monolayer graphene. We show that the 2D-Au ML is a semiconductor with the valence band maximum 50 meV below the Fermi level. The graphene and gold layers are largely non-interacting, thereby defining a class of van der Waals heterostructure. The 2D-Au bands, exhibit a 225 meV spin-orbit splitting along the ΓK direction, making it appealing for spin-related applications. By tuning the amount of gold at the SiC/graphene interface, we induce a semiconductor to metal transition in the 2D-Au, which has not yet been observed and hosts great interest for fundamental physics.
“…bringing atomic layers on or between graphene and the substrate. For example the charge carrier concentration was successfully changed by different layer thicknesses of Germanium and Au‐intercalation was shown to lead to a Rashba‐type spin‐orbit splitting . Bilayer graphene intercalated with calcium showed superconducting behavior at 4 K and further evidence for superconductivity in Li‐decorated monolayer graphene was reported .…”
The continuous progress in device miniaturization demands a thorough understanding of the electron transport processes involved. The influence of defects -discontinuities in the perfect and translational invariant crystal lattice -plays a crucial role here. For graphene in particular, they limit the carrier mobility often demanded for applications by contributing additional sources of scattering to the sample. Due to its two-dimensional nature graphene serves as an ideal system to study electron transport in the presence of defects, because one-dimensional defects like steps, grain boundaries and interfaces are easy to characterize and have profound effects on the transport properties. While their contribution to the resistance of a sample can be extracted by carefully conducted transport experiments, scanning probe methods are excellent tools to study the influence of defects locally. In this letter, the authors review the results of scattering at local defects in graphene and other 2D systems by scanning tunneling potentiometry, 4-point-probe microscopy, Kelvin probe force microscopy and conventional transport measurements. Besides the comparison of the different defect resistances important for device fabrication, the underlying scattering mechanisms are discussed giving insight into the general physics of electron scattering at defects.
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