Rapid synthesis of fluorescent single-chain nanoparticles via photoinduced step-growth polymerization of pendant carbazole units

Kilic, Deniz; Pamukcu, Ceren; Balta, Demet Karaca; Temel, Binnur Aydogan; Temel, Gokhan

doi:10.1016/j.eurpolymj.2019.109469

Cited by 12 publications

(9 citation statements)

References 37 publications

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“…If the star polymers contain different kinds of arms, they are generally referred to as Miktoarm CCS . The hydrophilic/hydrophobic arms afford solubility to the spherical shapes, while the cores can act as the location for template synthesis, or encapsulation of drugs, , fluorescence probes, , and catalytic sites. − …”

Section: Discussionmentioning

confidence: 99%

Single-Chain Polymer Nanoparticles for Addressing Morphologies and Functions at the Nanoscale: A Review

Nitti

Carfora

Assanelli

et al. 2022

ACS Appl. Nano Mater.

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This review discusses recent advances concerning morphologies and functions obtained from single-chain nanoparticles (SCNPs). SCNPs are unimolecular, soft nano-objects consisting of individual polymer chains collapsed to a certain degree by means of intramolecular bonding. Many of potential applications of SCNPs rely on their peculiar molecular morphology adopted in solution. SCNPs coming from random or block copolymers can yield ordered structures by self-assembly in a wide range of morphologies including spheres, cylinders, bicontinuous structures, lamellae, vesicles, and many other complex or hierarchical assemblies. These nanocomposites can provide practical applications, still in their infancy, in several fields. The classification of SCNPs according to their morphologies will help to link their function to the specific applications.

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Section: Discussionmentioning

confidence: 99%

Single-Chain Polymer Nanoparticles for Addressing Morphologies and Functions at the Nanoscale: A Review

Nitti

Carfora

Assanelli

et al. 2022

ACS Appl. Nano Mater.

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“…In an interesting work by Kilic et al., they synthesized a copolymer comprising of styrene and chloromethylstyrene monomers via nitroxide‐mediated radical polymerization. [ 86 ] Carbazole moieties were then introduced by post‐polymerization modification. The folding of the linear precursor polystyrene containing carbazole unites (PS‐Cr) was performed under UV light with the aid of diphenyliodonium hexafluorophosphate ( Figure ).…”

Section: Scnps Via Other Methodsmentioning

confidence: 99%

Section: Scnps Via Other Methodsmentioning

confidence: 99%

Synthetic Routes to Single Chain Polymer Nanoparticles (SCNPs): Current Status and Perspectives

Alqarni

Waldron

Yilmaz

et al. 2021

Macromol. Rapid Commun.

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Recent advances in polymer science make it possible to create single chain polymer nanoparticles (SCNPs), which can mimic the folding of natural macromolecules, such as protein and nucleic acid, in terms of their native and functional state. Even though considerable progress has been done during the last years, the synthesis of relatively controlled SCNPs with a good folding accuracy is still challenging due to lack of appropriate chemical synthesis techniques. Different types of SCNPs are developed with enhanced properties and used for various applications, e.g., delivery systems, imaging agents, and nanomedicine. As it is believed that SCNPs are so crucial to elucidate single chain technology, in this review, recent developments in SCNPs are discussed comprehensively according to their synthetic approaches to keep readers updated on this important research field. First, selective point folding methods are classified and highlighted, and then repeat unit folding routes are discussed with exciting examples.

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“…Therefore, ultra-small polymeric nanoparticles (sub-10 nm) can be formed using the corresponding operation. Various soft-nanoparticle architectures have been developed so far such as light-responsive compounds, [7][8][9][10] metal catalysts, 11,12 and size adjustable polymeric materials. 13,14 Besides, several synthetic methodologies have been conceived to achieve intramolecularly crosslinked polymeric products such as "click" chemistry, 15 photo-manipulated crosslinking 16,17 and supramolecular interactions.…”

Section: Introductionmentioning

confidence: 99%

Rapid synthesis of polyester based single-chain polymeric nanoparticles via an intra-molecular aza-Michael addition reaction

et al. 2022

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Rapid synthesis of fluorescent single-chain nanoparticles via photoinduced step-growth polymerization of pendant carbazole units

Cited by 12 publications

References 37 publications

Single-Chain Polymer Nanoparticles for Addressing Morphologies and Functions at the Nanoscale: A Review

Single-Chain Polymer Nanoparticles for Addressing Morphologies and Functions at the Nanoscale: A Review

Synthetic Routes to Single Chain Polymer Nanoparticles (SCNPs): Current Status and Perspectives

Rapid synthesis of polyester based single-chain polymeric nanoparticles via an intra-molecular aza-Michael addition reaction

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