Rapid Monitoring of Copper Over a Wide Concentration range by High-Sensitive Potentiometric Membrane Electrode Based on 1-cyano-1-piperidino-2(N- piperidino methyl)-cyclo hexane
Abstract:n this paper, 1-cyano-1-piperidino-2(N- piperidino meth-yl)-cyclohexane was synthesized. The lowest-energy conformer of this molecule (Ligand) with axial and equatorial forms of cyanide toward cyclohexane and local minima corresponding to their complexes with various ions were obtained using Monte Carlo procedure by Molecular Mechanics with MMFF94 method. The calculated results of the Gibbs free energy of the reaction using density functional theory (DFT) show that the thermodynamic reactivity of complexation … Show more
“…The chromium(III) sensors' selectivity coefficients were assessed by the well-known Matched Potential Method (MPM). [31][32][33] In MPM, rst the change in the potentials on altering the primary ion activity is measured. Then, adding the interfering ion to an identical reference solution is performed until the same potential change is obtained.…”
The present study deals with synthesis of N-(thiazol-2-ylcarbamothioyl) benzamide. It was utilized as a neutral ionophore for designing three types of chromium (III) sensors including coated wire ion selective electrodes...
“…The chromium(III) sensors' selectivity coefficients were assessed by the well-known Matched Potential Method (MPM). [31][32][33] In MPM, rst the change in the potentials on altering the primary ion activity is measured. Then, adding the interfering ion to an identical reference solution is performed until the same potential change is obtained.…”
The present study deals with synthesis of N-(thiazol-2-ylcarbamothioyl) benzamide. It was utilized as a neutral ionophore for designing three types of chromium (III) sensors including coated wire ion selective electrodes...
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