“…6. Each decay curve can be well fitted into a single exponential functional I(t) = I 0 + A 1 exp(Àt/s), where I and I 0 are the luminescence intensities at time t and 0, A 1 is a constant and s is the lifetime [23]. As shown, the lifetimes of the 1 G 4 state for Tm, Tm-Li, Tm@ and Tm-Li@ samples were determined to be 0.46, 0.52, 0.66 and 0.98 ms, respectively.…”
Section: Uc Luminescence Propertiesmentioning
confidence: 99%
“…Till now, numerous techniques have been adopted to further enhance UC emissions, including sensitizing mechanisms [15,16], crystal surface modifications [17,18], the formation of coreshell structure [19,20], the introduction of non-lanthanide ions [21][22][23][24][25][26] and the incorporation of noble-metals [27][28][29]. Among these methods, the growth of a shell surrounding the core is a common way to improve luminescence efficiency.…”
“…6. Each decay curve can be well fitted into a single exponential functional I(t) = I 0 + A 1 exp(Àt/s), where I and I 0 are the luminescence intensities at time t and 0, A 1 is a constant and s is the lifetime [23]. As shown, the lifetimes of the 1 G 4 state for Tm, Tm-Li, Tm@ and Tm-Li@ samples were determined to be 0.46, 0.52, 0.66 and 0.98 ms, respectively.…”
Section: Uc Luminescence Propertiesmentioning
confidence: 99%
“…Till now, numerous techniques have been adopted to further enhance UC emissions, including sensitizing mechanisms [15,16], crystal surface modifications [17,18], the formation of coreshell structure [19,20], the introduction of non-lanthanide ions [21][22][23][24][25][26] and the incorporation of noble-metals [27][28][29]. Among these methods, the growth of a shell surrounding the core is a common way to improve luminescence efficiency.…”
“…The remarkable challenge for us is how to further enhance the UC intensities of RE ions doped β-NaYF 4 crystals, which has considerable significance to their applications. So far, several attempts have been devoted to improving UC intensity via internal adjustment and external approaches, such as sensitizing mechanisms26, the formation of core-shell structure27, the introduction of non-lanthanide ions2829 and the incorporation of noble metals3031. Among these methods, co-doping with non-lanthanide ions provides an alternative approach to enhance UC luminescence intensity by adjusting the crystal field symmetry.…”
A strategy has been adopted for simultaneous morphology manipulation and upconversion luminescence enhancement of β-NaYF4:Yb3+/Er3+ microcrystals by simply tuning the KF dosage. X-ray power diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and photoluminescence spectra (PL) were used to characterize the samples. The influence of molar ratio of KF to Y3+ on the crystal phase and morphology has been systematically investigated and discussed. It is found that the molar ratio of KF to Y3+ can strongly control the morphology of the as-synthesized β-NaYF4 samples because of the different capping effect of F− ions on the different crystal faces. The possible formation mechanism has been proposed on the basis of a series of time-dependent experiments. More importantly, the upconversion luminescence of β-NaYF4:Yb3+/Er3+ was greatly enhanced by increasing the molar ratio of KF to RE3+ (RE = Y, Yb, Er), which is attributed to the distortion of local crystal field symmetry around lanthanide ions through K+ ions doping. This synthetic methodology is expected to provide a new strategy for simultaneous morphology control and remarkable upconversion luminescence enhancement of yttrium fluorides, which may be applicable for other rare earth fluorides.
“…So it is necessary to improve the luminescence intensity of UCNPs to meet the extremely high sensitivity requirements for bioassays and bioimaging. Up to date, several methods have been developed to enhance UC emission, including the manipulation of the dopant concentration [54][55][56], the control of particle size [57,58], the introduction of nonLn 3+ [59][60][61][62][63], the formation of core-shell structure [64][65][66][67][68][69][70][71][72][73][74][75][76][77][78][79][80][81][82][83] and the incorporation of noble-metals [84][85][86]. Some of these approaches have already been presented by previous review articles [87,88].…”
Section: Luminescence Enhancement Of Ucnpsmentioning
Multimodal nanoprobes that integrate different imaging modalities in one nano-system could offer synergistic effect over any modality alone to satisfy the higher requirements on the efficiency and accuracy for clinical diagnosis and medical research. Upconversion nanoparticles (UCNPs), particularly lanthanide (Ln)-based NPs have been regarded as an ideal building block for constructing multimodal bioprobes due to their fascinating properties. In this review, we first summarize recent advances in the optimizations of existing UCNPs. In particular, we highlight the applications of Ln-based UCNPs for multimodal cancer imaging in vitro and in vivo. The explorations of UCNPs-based multimodal nanoprobes for targeting diagnosis and imaging-guided therapeutics are also presented. Finally, the challenges and perspectives of Ln-based UCNPs in this rapid growing field are discussed.
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