Rapid dye degradation with reactive oxidants generated by chloride-induced peroxymonosulfate activation

Abstract

Transition-metal is known to catalyze peroxymonosulfate (PMS) decomposition to produce sulfate radicals. Here we report reactions between PMS and chloride, without a need of transition metals, also can be used to degrade organic dye pollutant (Rhodamine B, (RhB)). Some important operating parameters, such as dosages of PMS and Cl(-), pH of solution, temperature, ionic strength, and several common cations, were systematically investigated. Almost complete decoloration of RhB was achieved within 5 min ([PMS] = 0.5 mM, [Cl(-)] = 120 mM, and pH 3.0), and RhB bleaching rate increased with the increased dosages of both PMS and chloride ion, following the pseudo-first-order kinetic model. However, the total organic carbon (TOC) removal results demonstrated that the decoloration of RhB was due to the destruction of chromophore rather than complete degradation. RhB decoloration could be significantly accelerated due to the high ionic strength. Increasing of the reaction temperature from 273 K to 333 K was beneficial to the RhB degradation, and the activation energy was determined to be 32.996 kJ/mol. Bleaching rate of RhB with the examined cations increased with the order of NH4 (+) < Na(+) < K(+) < Al(3+) < Ca(2+) < Mg(2+). Some major degradation products of RhB were identified by GC-MS. The present study may have active technical implications for the treatment of dyestuff wastewater in practice.

On the kinetics of organic pollutant degradation with Co2+/peroxymonosulfate process: When ammonium meets chloride

“…As shown in Fig. 4(a) < Na + , which was similar to the previous studies (Lou et al, 2003). However, NH 4 + was the major species responsible for AO7 degradation with the molar ratio of varying from 2:1 to 10:1.…”

“…It is known that NH 4 + hydrolyzes into neutral amine which may react with SO 4 •forming NH 2 • (Eqs. 4 and 5), a relatively weak oxidant (E 0 (NH 2 • /NH 3 ) = 0.6 V) (Lou et al, 2003;Nakamura et al, 2014;Neta et al, 1988).…”

Transformations of chloro and nitro groups during the peroxymonosulfate-based oxidation of 4-chloro-2-nitrophenol

“…The nitrating agent-Å NO 2 is likely to be directly oxidized by PMS (E 0 (HSO 5 À /HSO 4 À ) = 1.85 V vs NHE) possessing a higher standard redox potential than H 2 O 2 (E 0 (H 2 O 2 /H 2 O) = 1.77 V vs NHE) (Cotton et al, 1999). For example, our previous studies Lou et al, 2013) demonstrated that PMS can directly oxidize Cl À through two-electron transfer, producing reactive halogens (e.g. Cl 2 /HClO) (Eqs.…”

Monochlorophenols degradation by UV/persulfate is immune to the presence of chloride: Illusion or reality?

“…Previous investigations have focused on the impact of Cl − ions on the performance of different AOPs [6,[10][11][12][13]. However, in most cases the applicability of the selected AOPs was evaluated by assessing the degradation efficiency in saline wastewater.…”