Rapid Construction of LTO/CuO Heterojunctions by Active Screen Plasma for Excellent Lithium-Ion Storage

Abstract

The lower intrinsic capacity and electron/ion transfer rate of Li 4 Ti 5 O 12 limit its application and commercialization in high-specific-energy batteries. In this work, Li 4 Ti 5 O 12 /CuO heterojunctions are constructed by depositing CuO ultrafine nanoparticles on Li 4 Ti 5 O 12 nanosheets using a controllable and high-efficiency active screen plasma (ASP) technique. It is found that the rich interface and built-in electric field provided by the heterojunction enhance the electron conductivity and ionic conductivity, and density functional theory calculations confirm that the heterojunction reduces the band gap and enhances the adsorption energy for lithium ions; in the lithium storage process, the conversion reaction between CuO and lithium ions not only provides additional capacity but also the product Cu facilitates electron transport and accelerates the electrochemical process. In addition, the increase in vacancies and specific surface area due to high-energy particle bombardment contributes to the increase in conductivity and the number of active sites, and the treated sample exhibits excellent reversible capacity (182.6 mAh•g −1 at 1C), high rate performance (170.6 mAh•g −1 at 30C), and long cycle stability (136.7 mAh•g −1 after 4500 cycles at 20C) in the half-cell, and the full cell assembled with NMC811 maintained 227.4 mAh•g −1 after 700 cycles at 1C.

Plasma-Induced Defect Engineering in TiNb2O7 for Boosting Lithium-Ion Diffusion

“…31,32 In addition, the energy exchange caused by the bombardment of high-energy particles allows behavior such as heterojunctions to be achieved at lower threshold temperatures. 33 Du et al constructed a defect-rich twodimensional p−n heterojunction by in situ plasma modification. The heterostructured Zn−N 2 cell exhibited ultrahigh power output and energy density in 0.1 M HCl solution (240 mA•h•g −1 ).…”

“…A power density of up to 109.8 mW cm –2 with no less than 300 stable cycles is presented at the negative electrode in an all-solid-state zinc–air battery . If the bombardment energy is higher than the atomic binding energy of the material surface, it can cause atoms to spill out of the material surface and create structural defects such as vacancies. , In addition, the energy exchange caused by the bombardment of high-energy particles allows behavior such as heterojunctions to be achieved at lower threshold temperatures . Du et al constructed a defect-rich two-dimensional p–n heterojunction by in situ plasma modification.…”