2018
DOI: 10.1021/acscombsci.7b00171
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Rapid Construction of Fe–Co–Ni Composition-Phase Map by Combinatorial Materials Chip Approach

Abstract: One hundred nanometer thick Fe-Co-Ni material chips were prepared and isothermally annealed at 500, 600, and 700 °C, respectively. Pixel-by-pixel composition and structural mapping was performed by microbeam X-ray at synchrotron light source. Diffraction images were recorded at a rate of 1 pattern/s. The XRD patterns were automatically processed, phase-identified, and categorized by hierarchical clustering algorithm to construct the composition-phase map. The resulting maps are consistent with corresponding is… Show more

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Cited by 47 publications
(21 citation statements)
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“…1a, the combinatorial thin-film precursor covering the entire composition range of Ti–Ni–Cu ternary system, were deposited following a procedure described by Xing et al . 33 on quartz glass substrates (25.4 mm × 25.4 mm × 2 mm) using a custom-designed high-throughput combinatorial ion beam deposition system (HTC-IBD) at room temperature with a base vacuum pressure of 1 × 10 −6 torr. The ternary thin-film precursor consisted of a sequentially deposited stack of wedge-shaped layers, that were created by a mask moving linearly across the substrate during deposition.…”
Section: Resultsmentioning
confidence: 99%
“…1a, the combinatorial thin-film precursor covering the entire composition range of Ti–Ni–Cu ternary system, were deposited following a procedure described by Xing et al . 33 on quartz glass substrates (25.4 mm × 25.4 mm × 2 mm) using a custom-designed high-throughput combinatorial ion beam deposition system (HTC-IBD) at room temperature with a base vacuum pressure of 1 × 10 −6 torr. The ternary thin-film precursor consisted of a sequentially deposited stack of wedge-shaped layers, that were created by a mask moving linearly across the substrate during deposition.…”
Section: Resultsmentioning
confidence: 99%
“…The literature proposes various approaches to fabricate combinatorial coatings, most of them being suitable only to a limited class of compounds. Among these, we can mention several physicalchemical deposition methods such as magnetron co-sputtering deposition [141], glancing angle deposition [142], co-electrodeposition [143], casting processes [144], or flow-coating methods [145]. An advanced experimental design could be envisioned in order to generate multi-compositional diagram 2D maps on high surface areas.…”
Section: Combinatorial Laser Technologiesmentioning
confidence: 99%
“…The technique used in this work provides the capability of measuring more than 5000 samples per day using a synchrotron x-ray diffraction and fluorescence for rapid characterization. Xing et al recently pushed the efficiency and automation even further [70]. The rate of recording diffraction images reached one pattern per second and the diffraction patterns were automatically processed to create the composition-phase map.…”
Section: Composition and Structurementioning
confidence: 99%