“…Compared with most of the recent reports on L/D-Arg recognition (Table S1 †), this enantiomer sensing device showed obvious advantages, such as easy operation, low cost, and a lower LOD value. [49][50][51][52] To demonstrate the chiral selectivity of the as-proposed asymmetric membrane for identifying Arg enantiomers, the recognition performance for other enantiomers, i.e., L/D-glutamic acid (L/D-Glu), L/D-phenylalanine (L/D-Phe), and L/D-histidine (L/D-His) was evaluated. For comparison, the chiral recognition ability of b-CD/TiO 2 M was also tested (Fig.…”
Section: Signal Magnication In I-v Curves For Chiral Recognitionmentioning
As an intriguing and intrinsic feature of life, chirality is highly associated with many significant biological processes. Simultaneous recognition and quantification of enantiomers remains a major challenge. Here, a sensitive...
“…Compared with most of the recent reports on L/D-Arg recognition (Table S1 †), this enantiomer sensing device showed obvious advantages, such as easy operation, low cost, and a lower LOD value. [49][50][51][52] To demonstrate the chiral selectivity of the as-proposed asymmetric membrane for identifying Arg enantiomers, the recognition performance for other enantiomers, i.e., L/D-glutamic acid (L/D-Glu), L/D-phenylalanine (L/D-Phe), and L/D-histidine (L/D-His) was evaluated. For comparison, the chiral recognition ability of b-CD/TiO 2 M was also tested (Fig.…”
Section: Signal Magnication In I-v Curves For Chiral Recognitionmentioning
As an intriguing and intrinsic feature of life, chirality is highly associated with many significant biological processes. Simultaneous recognition and quantification of enantiomers remains a major challenge. Here, a sensitive...
“…[1][2][3] The ability to recognize substrates and form supramolecular complexes with them underlies the use of such compounds in sensory techniques and technology. [4][5][6] As well, the unique spatial structure of calix [4] arene allows the formation of so-called inherently chiral compounds, the chirality of which is based on the absence of planes of symmetry or the center of inversion due to the asymmetric placement of several achiral groups on the macrocyclic platform. Recently, special attention has been paid to such compounds.…”
Section: Introductionmentioning
confidence: 99%
“…Calixarenes are widely used as molecular platforms for the design of specific receptors which are capable of high selectivity to recognize substrates close in size and properties—various cations, anions, and neutral molecules 1–3 . The ability to recognize substrates and form supramolecular complexes with them underlies the use of such compounds in sensory techniques and technology 4–6 . As well, the unique spatial structure of calix[4]arene allows the formation of so‐called inherently chiral compounds, the chirality of which is based on the absence of planes of symmetry or the center of inversion due to the asymmetric placement of several achiral groups on the macrocyclic platform.…”
The enantiodiscrimination properties of stereomerically pure inherently chiral calix[4]arene acetic acids, as well as their esters and amides in relation to 1-phenylethylamine stereoisomers in liquid and gaseous phases were studied by means of proton magnetic resonance spectroscopy ( 1 H NMR) and quartz crystal microbalance (QCM) techniques. Series of QCM sensors with thin films of inherently chiral calix[4]arenes, immobilized on the quartz resonator surfaces by spin-coating and spreading drop methods have been fabricated. It was shown that sensors based on calix[4]arene acetic acids are able to recognize Rand S-forms of 1-phenylethylamine in gaseous phase under concentration level of 10-400 ppm.
“…At present, QCM immunosensor has been widely used in clinical testing, food hygiene, environmental testing, as well as other fields of chemical analysis, and biological analysis. The detection of bacteria by QCM is a new and attractive Research Topic in electronic informatics and medicine (Muckley et al, 2016 ; Tai et al, 2016 ; Chen et al, 2018 ; Ding et al, 2018 ; Lal and Tiwari, 2018 ; Temel et al, 2019 ).…”
In this work, a quartz crystal microbalance (QCM) sensor has been fabricated using immunoassay for sensitive determination of Bifidobacterium bifidum. Au nanoparticle has been used for amplifying sandwich assays. The proposed immunosensor exhibited a linear detection range between 10 3 and 10 5 CFU/mL with a limit of detection of 2.1 × 10 2 CFU/mL. The proposed immunosensor exhibited good selectivity for B. bifidum sensing with low cross reactivity for other foodborne pathogens such as Lactobacillus acidophilus, Listeria monocytogenes, and Escherichia coli. In addition, the proposed immunosensor has been successfully used for B. bifidum detection in feces samples and food samples. The frequency decreases of 12, 17, and 10 Hz were observed from the milk samples consisting of the mixtures of L. acidophilus, L. monocytogenes, and E. coli. The frequency decreases of 8, 15, and 7 Hz were observed from the feces samples consisting of the mixtures of L. acidophilus, L. monocytogenes, and E. coli.
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