Raman spectroscopic study of olivine-group minerals

Mouri, Takashi; Enami, Masaki

doi:10.2465/jmps.071015

Cited by 110 publications

(114 citation statements)

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“…1 and eqn. 2 are consistent with previously published results (e.g., Wang et al, 2004;Mouri and Enami, 2008). Several studies showed that the relations between the peak positions and Mg# are not linear in the case of both peak 1 and peak 2 (Kuebler et al, 2007;Mouri and Enami, 2008) or that the regression can be divided into two Mg# regions (Gaisler and Kolesov, 2007).…”

Section: Mg# Dependencesupporting

confidence: 82%

“…Understanding the relationship among the Raman peak positions, Mg#, and residual pressure enables a simultaneous determination of both Mg# and residual pressure. The relationship between the peak positions and Mg# of olivine has been examined under ambient pressure (e.g., Wang et al, 2004;Kuebler et al, 2006;Gaisler and Kolesov, 2007;Mouri and Enami, 2008). In contrast, the pressure dependence of the Raman spectra of olivine has been examined only for forsterite (e.g., Chopelas et al, 1990;Wang et al, 1993;Durben et al, 1993) and for olivine with Mg# of 90 (e.g., Besson et al, 1982;Rouquette et al, 2008); no systematical study on various Mg# has been reported.…”

Section: Introductionmentioning

confidence: 99%

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Simultaneous determination of Mg# and residual pressure in olivine using micro-Raman spectroscopy

Yasuzuka

Ishibashi

Arakawa

et al. 2009

Journal of Mineralogical and Petrological Sciences

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We measured the Raman spectra of Fe -Mg olivine grains with Mg# [= 100 × Mg/(Mg + Fe)] values ranging from 80 -100 under a pressure of up to 4 GPa using a diamond anvil cell (DAC). We focused on a relatively weak peak at around 547 cm −1 , denoted as peak 0, and two intense peaks at around 825 cm −1 (peak 1) and 857 cm −1 (peak 2). The peak position (κ) of each peak shifted upward linearly as Mg# and pressure increased; the Mg# derivatives (∂κ/∂Mg#) for peak 0, peak 1, and peak 2 under ambient pressure were 0.496, 0.184, and 0.227 cm −1 /Mg#, respectively. The pressure derivatives (∂κ/∂P) for peak 0, peak 1, and peak 2 were 1.558 -2.08, 3.38 -3.46, and 3.20 -3.35 cm −1 /GPa, respectively. The value of ∂κ/∂P for peak 0 decreased as Mg# increased, whereas those for peak 1 and peak 2 were almost constant against Mg#. The peak positions of peak 0, peak 1, and peak 2 were formulated as functions of Mg# and pressure based on the results. We found that when the ranges of Mg# and pressure are limited to 85 -100 and 0 -1 GPa, the combination of peak 0 and peak 1 reproduced the original observed data with an error of ± 0.9 for Mg# and an error of ± 0.09 GPa for residual pressure. We applied these functions to a natural olivine inclusion in a diamond obtained from Internationalnaya pipe, Yakutia, Siberia, Russia, and obtained reasonable values of Mg# and pressure-91.6 ± 0.6 Mg# and 0.32 ± 0.05 GPa, respectively.

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Section: Mg# Dependencesupporting

confidence: 82%

Section: Introductionmentioning

confidence: 99%

Simultaneous determination of Mg# and residual pressure in olivine using micro-Raman spectroscopy

Yasuzuka

Ishibashi

Arakawa

et al. 2009

Journal of Mineralogical and Petrological Sciences

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“…When the ion concentration exceeds a few wt% (locally), olivine silicate (Co 2 SiO 4 ) or cobalt aluminate spinel (CoAl 2 O 4 ) precipitates out [45,46], in both lead-based (soft paste) or silica-rich (hard paste) glazes respectively. The olivine Raman signature has doublet at about 825 cm -1 [68].…”

Section: Raman Signaturesmentioning

confidence: 99%

Non-invasive Raman analyses of Chinese huafalang and related porcelain wares. Searching for evidence for innovative pigment technologies

Colomban

Zhang

Zhao

2017

Ceramics International

104

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Eighteen Chinese painted enamelled porcelains and three Chinese enamelled Yixing stonewares dated to the 16 th to 19 th centuries and kept at the Musée national des arts asiatiques-Guimet (MNAAG), have been analysed with a mobile Raman set-up to identify their enamelling technology. Different Grand Feu (leadless or lead-poor colourless and blue enamel) and Petit Feu (lead-rich red (hematite), yellow and green (Pb-Sn/Sb/X pyrochlore) and black enamels) glazes were respectively identified on wares from the wucai group, the Famille verte group, and the huafalang group. Calcium phosphate was detected in a 17 th century vase as a rare opacifier. Cassiterite was identified in the light green glaze of an imperial huafalang bowl dated to the final period of the Kangxi reign (1662-1722), ca. the 1 st quarter of the 18 th century. Lead arsenate was identified in the blue glaze of two artefacts, a huafalang bowl and a painted enamel water dropper, and in the blue enamel of a 19 th century Yixing teapot. Lead arsenate found in some of the blue enamels appears to arise from the arsenic content in Erzgebirge cobalt ores and not due to voluntary addition. This may prove the use of raw materials or enamel powder imported from Europe in developing these opaque colours. The use of lead arsenate as white opacifier is clear for a water dropper bearing the Yongzheng emperor's mark (r. 1723-1735). The technological palette appears different for the artefacts expected to originate from the same period and provenance (imperial workshop) which is consistent with a period of intense innovation, open to technological skill from abroad -i.e. from French/European painted enamel technology -as revealed by ancient French (Jesuits) and Chinese historical reports. Graphical abstract 2

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“…1: actually the black area appears dark blue under high-power illumination). The Raman spectrum of olivine (Co 2 SiO 4 ) also exhibits its stretching doublet in the same wavenumber range [47], but the peak bandwidth is much narrower. The intensity of Si-O stretching tends to be much lower than that of As-O because of the smaller polarizability and the lower number of electrons involved in the bond.…”

Section: Pigmentsmentioning

confidence: 99%

On-site Raman analysis of 17th and 18th century Limoges enamels: Implications on the European cobalt sources and the technological relationship between Limoges and Chinese enamels

Colomban

Arberet

Kırmızı

2017

Ceramics International

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International audienceLimoges enamels on metal from the 17th to 18th centuries were analysed by non-invasive Raman microspectrometry with a mobile set-up in storage at the Musée des Arts Décoratifs (Paris) in order to identify the types of glazes and pigments used and to compare them with those found in Chinese cloisonné and falangcai enamels painted on metal and porcelain from the Kangxi and Yongzheng reigns (Qing dynasty). Certain French Jesuit and Chinese historical records report exchanges of technical know-how and artefacts during this period from France to China. Particular attention is paid to the detection of lead arsenate in blue and white enamels as well as in the whitened ones. Lead arsenate appears to be formed in blue enamels due to the high arsenic content of European cobalt ores exploited during the period in question

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Raman spectroscopic study of olivine-group minerals

Abstract: , respectively, and their ω (= κ 1 -κ 2 ) value is fairly constant around 32 cm. On the other hand, fayalite, tephroite, and other olivine -group minerals in which transition elements exist in the M2 site have a fairly constant κ 1 (836 -839 cm

Cited by 110 publications

References 19 publications

Simultaneous determination of Mg# and residual pressure in olivine using micro-Raman spectroscopy

Simultaneous determination of Mg# and residual pressure in olivine using micro-Raman spectroscopy

Non-invasive Raman analyses of Chinese huafalang and related porcelain wares. Searching for evidence for innovative pigment technologies

On-site Raman analysis of 17th and 18th century Limoges enamels: Implications on the European cobalt sources and the technological relationship between Limoges and Chinese enamels

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