2006
DOI: 10.1063/1.2422897
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Raman scattering in InAs nanowires synthesized by a solvothermal route

Abstract: Micro-Raman scattering experiment has been performed to study solvothermally synthesized InAs nanowires with different diameters. Strong low frequency branch of the LO-phonon-plasmon mode (L−) was observed. The longitudinal optic (LO) mode was found to be dependent on diameter of the nanowires. The wave vector uncertainty and the carrier concentration related Fermi-Thomas screening effect were proposed to play important roles for this phenomenon. Laser heating, phonon confinement, surface defects, together wit… Show more

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Cited by 17 publications
(12 citation statements)
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“…29,34,36 In NW geometries, the spatial confinement of free electron gases in the radial direction causes an additional contribution to the wave-vector nonconservation. 37 In order to simulate the experimental spectra, the contribution of the charge-density fluctuation (CDF) and the impurity-induced Fr€ ohlich (IIF) mechanisms were taken into account. The details of the lineshape calculations are given in Refs.…”
Section: Resultsmentioning
confidence: 99%
“…29,34,36 In NW geometries, the spatial confinement of free electron gases in the radial direction causes an additional contribution to the wave-vector nonconservation. 37 In order to simulate the experimental spectra, the contribution of the charge-density fluctuation (CDF) and the impurity-induced Fr€ ohlich (IIF) mechanisms were taken into account. The details of the lineshape calculations are given in Refs.…”
Section: Resultsmentioning
confidence: 99%
“…[24] Similar standing-wave patterns are observed for a range of nanowires. [12,25] More interestingly, we find the diameter of nanowire provides a means to control the plasmonic properties such as the wavelength (Figure 2l electromagnetic modes guided by dielectric fibers, which show opposite changing trends. Our InAs nanowires are unintentionally doped during the fabrication process.…”
Section: Inas Plasmonsmentioning
confidence: 89%
“…However, the interpretation of the Raman peaks and their relation to carrier density are often far from being straightforward. Indeed, LO modes can be screened by the free electron plasma from surface accumulation layers, in which case LPP modes cannot be observed unless the phonon wave‐vector uncertainty surpasses the Thomas–Fermi screening wave‐vector 33. In this case, the observation of LPP modes depends both on NW diameter and doping.…”
Section: Nanowire Ensemblesmentioning
confidence: 99%
“…Besides providing information about structural and crystallographic characteristics, electronic properties of nanowires can be accessed by inelastic scattering mediated by the coupling of phonons and plasmons 7, 8, 30–33, which are Raman active and have a frequency that shifts with carrier concentration. Details about the electronic band structure can as well be accessed under resonant conditions, by tuning the energy of the incoming or scattered light to the electronic transitions of the nanowire 34–38.…”
Section: Introductionmentioning
confidence: 99%