Raman and infrared spectra and normal coordinates of the trifluoromethanesulfonate and trichloromethanesulfonate anions

The Relative Coordinating Ability of Some Weak O‐Donor Anions and Water Towards the [Pt(terpy)]2+ (terpy = 2,2′:6′,2″‐terpyridine) Center – X‐ray Crystal Structures of [Pt(terpy)(H2O)](CF3SO3)2 and [Pt2(μ‐OH)(terpy)2](PF6)2(CF3SO3)

“…This increase in the multiplicity is typical of methanesulfonato complexes and is a consequence of a lowering of the symmetry of the SO 3 group upon coordination. [14] The analytical data for the acidolysis reaction product when Y = NO 3 + . In particular, the doublet at δ = 8.58 ppm, which is not present in the 1 H NMR spectra of the methanesulfonato complexes, is attributable to the H 6 terpy protons of [Pt(ONO 2 )(terpy)] + .…”

Metallocene and Organo-main Group Trifluoromethanesulfonates

“…These bands are usually sufficient to indicate the mode of bonding. The ionic triflate salts of Ba 2+ , Na + , and Ag + have been characterized by IR spectroscopy here and by others [8,9]. Four distinct peaks are evident (near 1040, 1180, 1230 and 1280 cm )1 ), which are the asymmetric and symmetric stretches of both the SO 3 and CF 3 groups.…”

New complexes of the hydronium ion with crown ethers: synthesis and vibrational spectra

“…18C6.CF3S03-complex in the region below 1500 cm-' (Fig. 4) are dominated by the strong bands of the anion, whose frequencies are slightly lower than in solid NaCF3S03 and Ba(CF3S03),, and in a concentrated aqueous solution of the CF3S03-ion (21 regions of the spectra which are free of the bands of the anions, the vibrational bands of the crown ether are very similar to those in the BF4-and C10,-complexes, which suggests that the 18C6.H30t adduct has the same overall geometry in all three cases.…”