Radical Polymerization: Reversing the Irreversible?

Barner‐Kowollik, Christopher

doi:10.1002/anie.200905145

Cited by 4 publications

(3 citation statements)

References 13 publications

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“…It happens that the present report addresses a recent mentioning that 'it is paramount to elucidate which reactions occur immediately after the birth of the primary radicals before the reaction with monomer units' [17].…”

Section: Discussionmentioning

confidence: 77%

Cage Effect Dynamics under Photolysis of Photoinitiators

Khudyakov¹,

Turro

2010

Designed Monomers and Polymers

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The efficiency of photoinitiators depends upon the quantum yield of photogeneration of reactive free radicals and the cage effect value. Only radicals that escape the cage can initiate free radical polymerization. The modern concept of the cage effect is presented. Dependencies of the cage effect upon increasing of solvent viscosity in the course of polymerization are discussed. Cage effect dynamics or kinetics of geminate recombination is of special interest. Results of a kinetic study on the cage effect using ns laser flash photolysis are described.

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Section: Discussionmentioning

confidence: 77%

Cage Effect Dynamics under Photolysis of Photoinitiators

Khudyakov¹,

Turro

2010

Designed Monomers and Polymers

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“…Reversible addition–fragmentation chain transfer (RAFT) has emerged as a promising controlled radical polymerization technique due to its versatility and simplicity and the advantage that the resulting polymer is free from the contamination of metal catalyst. − Also, RAFT is compatible with almost all of the conventional radical polymerization monomers. Taking advantage of this polymerization technique, after anchoring CTA onto silica nanoparticles, different polymer brushes based on silica nanoparticles are reported by Benicewicz, , Brittain, , Zhao, , Pan, and Perrier et al…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Well-Defined Photo-Cross-Linked Polymeric Nanocapsules by Surface-Initiated RAFT Polymerization

et al. 2011

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“…Kowollik, Du Prez, Espeel, Hawker, Junkers, Schlaad, and Van Camp have reported the most important criteria for a successful click reaction in macromolecular synthesis [64] in addition to requirements defined by Sharpless. [2] These extra requirements can be classified under equimolarity, large-scale purification, fast time scale, high yields, and stable compounds together with criteria defined by Sharpless (Scheme 10).…”

Section: Discussionmentioning

confidence: 99%

Click and Multicomponent Reactions Work Together for Polymer Chemistry

Tunca

2018

Macro Chemistry & Physics

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This article investigates the current combinations of click and multicomponent reactions (MCRs) to produce complex macromolecular structures through polymer–polymer conjugation or hetero‐functionalization of polymers. The click and MCRs display similar features covering the equimolarity, fast time scale, high yields, stable compounds, modular, orthogonal and single reaction trajectory. Of classical click reactions, CuAAC, Diels–Alder, thiol‐ene (‐yne), and nucleophilic substitution on perfluoroaryl groups reactions are combined with MCRs, namely, Passerini, Ugi, or Biginelli reactions. It should be noted that these combinations can afford the target polymer structures, which are not attainable by employing one of these reactions alone.

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Radical Polymerization: Reversing the Irreversible?

Cited by 4 publications

References 13 publications

Cage Effect Dynamics under Photolysis of Photoinitiators

Cage Effect Dynamics under Photolysis of Photoinitiators

Synthesis of Well-Defined Photo-Cross-Linked Polymeric Nanocapsules by Surface-Initiated RAFT Polymerization

Click and Multicomponent Reactions Work Together for Polymer Chemistry

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