Transparent passive cooling materials can cool targets
environmentally
without interfering with light transmission or visual information
reception. They play a prominent role in solar cells and flexible
display cooling. However, achieving potent transparent cooling remains
challenging, because light transmission is accompanied by thermal
energy. Here we propose to realize effective passive cooling in transparent
materials via a microscale phase separation hydrogel film. The poly(N-isopropylacrylamide-co-acrylamide) hydrogel
presents light transmittance of >96% and infrared emissivity as
high
as 95%. The microphase-separated structure affords a higher enthalpy
of evaporation. The film is highly adhesive. In field applications,
it reduces temperatures by 9.14 °C compared to those with uncovered
photovoltaic panels and 7.68 °C compared to those for bare flexible
light-emitting diode screens. Simulations indicate that energy savings
of 32.76–51.65 MJ m–2 year–1 can be achieved in typical tropical monsoon climates and temperate
continental climates. We expect this work to contribute to energy-efficient
materials and a carbon-neutral society.