A novel theory of radiative electron capture in second forbidden non-unique transition, is applied to reanalyze experimental data obtained previously for the decay of 59 Ni. The measured gamma spectrum is shown to be distorted at the high-energy end, presenting the first direct evidence for the virtual beta-gamma transition through the excited state in 59 Co. The complete theoretical predictions, including both the direct and the virtual decay channels, as well as the interference between them, reproduce very well the experimental spectrum. The virtual nuclear component amounts to about 4% of the total gamma intensity.